1: 1 Cross-assembly of two β-diketonate complexes through arene-perfluoroarene interactions

Akiko Hori, Ayaka Shinohe, Mikio Yamasaki, Eiji Nishibori, Shinobu Aoyagi, Makoto Sakata

Research output: Contribution to journalArticle

  • 30 Citations

Abstract

(Figure Presented) Stack 'em up: Two coordination complexes - one a perfluoroarene-functionalized β-diketonate copper complex (purple, see picture), the other an arene-functionalized metal (M = Cu, Pd, Pt) complex (green) - form alternately layered arrays through arene-perfluoroarene interactions with metal-to-metal distances close to van der Waals contacts to give 1:1 cocrystals as one-dimensional metal wires.

LanguageEnglish
Pages7617-7620
Number of pages4
JournalAngewandte Chemie - International Edition
Volume46
Issue number40
DOIs
StatePublished - 2007
Externally publishedYes

Fingerprint

Metals
Coordination Complexes
Copper
Wire

Keywords

  • Copper
  • Crystal engineering
  • Electrostatic interactions
  • Fluorinated ligands
  • Self-assembly

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

1 : 1 Cross-assembly of two β-diketonate complexes through arene-perfluoroarene interactions. / Hori, Akiko; Shinohe, Ayaka; Yamasaki, Mikio; Nishibori, Eiji; Aoyagi, Shinobu; Sakata, Makoto.

In: Angewandte Chemie - International Edition, Vol. 46, No. 40, 2007, p. 7617-7620.

Research output: Contribution to journalArticle

Hori, A, Shinohe, A, Yamasaki, M, Nishibori, E, Aoyagi, S & Sakata, M 2007, '1: 1 Cross-assembly of two β-diketonate complexes through arene-perfluoroarene interactions' Angewandte Chemie - International Edition, vol 46, no. 40, pp. 7617-7620. DOI: 10.1002/anie.200702662
Hori, Akiko ; Shinohe, Ayaka ; Yamasaki, Mikio ; Nishibori, Eiji ; Aoyagi, Shinobu ; Sakata, Makoto. / 1 : 1 Cross-assembly of two β-diketonate complexes through arene-perfluoroarene interactions. In: Angewandte Chemie - International Edition. 2007 ; Vol. 46, No. 40. pp. 7617-7620
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