1:1 Cross-assembly of two β-diketonate complexes through arene-perfluoroarene interactions

Akiko Hori; Ayaka Shinohe; Mikio Yamasaki; Eiji Nishibori; Shinobu Aoyagi; Makoto Sakata

doi:10.1002/anie.200702662

1:1 Cross-assembly of two β-diketonate complexes through arene-perfluoroarene interactions

Akiko Hori, Ayaka Shinohe, Mikio Yamasaki, Eiji Nishibori, Shinobu Aoyagi, Makoto Sakata

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

(Figure Presented) Stack 'em up: Two coordination complexes - one a perfluoroarene-functionalized β-diketonate copper complex (purple, see picture), the other an arene-functionalized metal (M = Cu, Pd, Pt) complex (green) - form alternately layered arrays through arene-perfluoroarene interactions with metal-to-metal distances close to van der Waals contacts to give 1:1 cocrystals as one-dimensional metal wires.

Original language	English
Pages (from-to)	7617-7620
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	40
DOIs	https://doi.org/10.1002/anie.200702662
Publication status	Published - 2007
Externally published	Yes

Keywords

Copper
Crystal engineering
Electrostatic interactions
Fluorinated ligands
Self-assembly

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200702662

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title = "1:1 Cross-assembly of two β-diketonate complexes through arene-perfluoroarene interactions",

abstract = "(Figure Presented) Stack 'em up: Two coordination complexes - one a perfluoroarene-functionalized β-diketonate copper complex (purple, see picture), the other an arene-functionalized metal (M = Cu, Pd, Pt) complex (green) - form alternately layered arrays through arene-perfluoroarene interactions with metal-to-metal distances close to van der Waals contacts to give 1:1 cocrystals as one-dimensional metal wires.",

keywords = "Copper, Crystal engineering, Electrostatic interactions, Fluorinated ligands, Self-assembly",

author = "Akiko Hori and Ayaka Shinohe and Mikio Yamasaki and Eiji Nishibori and Shinobu Aoyagi and Makoto Sakata",

year = "2007",

doi = "10.1002/anie.200702662",

language = "English",

volume = "46",

pages = "7617--7620",

journal = "Angewandte Chemie - International Edition",

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T1 - 1:1 Cross-assembly of two β-diketonate complexes through arene-perfluoroarene interactions

AU - Hori, Akiko

AU - Shinohe, Ayaka

AU - Yamasaki, Mikio

AU - Nishibori, Eiji

AU - Aoyagi, Shinobu

AU - Sakata, Makoto

PY - 2007

Y1 - 2007

N2 - (Figure Presented) Stack 'em up: Two coordination complexes - one a perfluoroarene-functionalized β-diketonate copper complex (purple, see picture), the other an arene-functionalized metal (M = Cu, Pd, Pt) complex (green) - form alternately layered arrays through arene-perfluoroarene interactions with metal-to-metal distances close to van der Waals contacts to give 1:1 cocrystals as one-dimensional metal wires.

AB - (Figure Presented) Stack 'em up: Two coordination complexes - one a perfluoroarene-functionalized β-diketonate copper complex (purple, see picture), the other an arene-functionalized metal (M = Cu, Pd, Pt) complex (green) - form alternately layered arrays through arene-perfluoroarene interactions with metal-to-metal distances close to van der Waals contacts to give 1:1 cocrystals as one-dimensional metal wires.

KW - Copper

KW - Crystal engineering

KW - Electrostatic interactions

KW - Fluorinated ligands

KW - Self-assembly

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DO - 10.1002/anie.200702662

M3 - Article

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AN - SCOPUS:35048816878

SN - 1433-7851

VL - 46

SP - 7617

EP - 7620

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 40

ER -

1:1 Cross-assembly of two β-diketonate complexes through arene-perfluoroarene interactions

Abstract

Keywords

ASJC Scopus subject areas

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