1:1 Cross-assembly of two β-diketonate complexes through arene-perfluoroarene interactions

Akiko Hori, Ayaka Shinohe, Mikio Yamasaki, Eiji Nishibori, Shinobu Aoyagi, Makoto Sakata

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

(Figure Presented) Stack 'em up: Two coordination complexes - one a perfluoroarene-functionalized β-diketonate copper complex (purple, see picture), the other an arene-functionalized metal (M = Cu, Pd, Pt) complex (green) - form alternately layered arrays through arene-perfluoroarene interactions with metal-to-metal distances close to van der Waals contacts to give 1:1 cocrystals as one-dimensional metal wires.

Original languageEnglish
Pages (from-to)7617-7620
Number of pages4
JournalAngewandte Chemie - International Edition
Volume46
Issue number40
DOIs
Publication statusPublished - 2007 Oct 16

Keywords

  • Copper
  • Crystal engineering
  • Electrostatic interactions
  • Fluorinated ligands
  • Self-assembly

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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