A benzene-rich pseudopolymorph of bis-[μ-1,3-bis-(penta-fluoro-phen-yl) prop-ane-1,3-dionato]-K3 O,O′: O′;K3 O:O,O′-bis-{aqua[1,3-bis-(penta-fluoro-phen-yl)propane-1,3-dionato-K 2 O,O′]nickel(II)} benzene tetra-solvate

Akiko Hori, Masaya Mizutani

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The title complex comprises two Ni2+ ions, four fluorinated ligands and two water mol-ecules in a centrosymmetric dinuclear complex. This compound was crystallized from benzene-CH2Cl2, and two types of crystals, viz. the title benzene tetra-solvate, [Ni2(C 15HF10O2)4(H2O) 2]·4C6H6, (I), and the previously reported benzene disolvate, [Ni2(C15HF10O 2)4(H2O)2]·2C 6H6, (II) [Hori et al. (2009). Bull. Chem. Soc. Jpn, 82, 96-98], were obtained as pseudopolymorphs. In the crystal structure of (I), the four benzene solvent mol-ecules inter-act closely with all the penta-fluoro-phenyl groups of the complex through arene-perfluoro-arene inter-actions. The mol-ecular structures of the two compounds show essentially the same conformation, although the benzene mol-ecules are accommodated in a columnar packing in (I), while they are isolated from each other in (II).

Original languageEnglish
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume65
Issue number11
DOIs
Publication statusPublished - 2009
Externally publishedYes

Fingerprint

Propane
Benzene
Nickel
Conformations
Crystal structure
Ions
Ligands
Crystals
Water

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

@article{42119f3382f6481ebf450d65a6cd570b,
title = "A benzene-rich pseudopolymorph of bis-[μ-1,3-bis-(penta-fluoro-phen-yl) prop-ane-1,3-dionato]-K3 O,O′: O′;K3 O:O,O′-bis-{aqua[1,3-bis-(penta-fluoro-phen-yl)propane-1,3-dionato-K 2 O,O′]nickel(II)} benzene tetra-solvate",
abstract = "The title complex comprises two Ni2+ ions, four fluorinated ligands and two water mol-ecules in a centrosymmetric dinuclear complex. This compound was crystallized from benzene-CH2Cl2, and two types of crystals, viz. the title benzene tetra-solvate, [Ni2(C 15HF10O2)4(H2O) 2]·4C6H6, (I), and the previously reported benzene disolvate, [Ni2(C15HF10O 2)4(H2O)2]·2C 6H6, (II) [Hori et al. (2009). Bull. Chem. Soc. Jpn, 82, 96-98], were obtained as pseudopolymorphs. In the crystal structure of (I), the four benzene solvent mol-ecules inter-act closely with all the penta-fluoro-phenyl groups of the complex through arene-perfluoro-arene inter-actions. The mol-ecular structures of the two compounds show essentially the same conformation, although the benzene mol-ecules are accommodated in a columnar packing in (I), while they are isolated from each other in (II).",
author = "Akiko Hori and Masaya Mizutani",
year = "2009",
doi = "10.1107/S0108270109037184",
language = "English",
volume = "65",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",
number = "11",

}

TY - JOUR

T1 - A benzene-rich pseudopolymorph of bis-[μ-1,3-bis-(penta-fluoro-phen-yl) prop-ane-1,3-dionato]-K3 O,O′

T2 - O′;K3 O:O,O′-bis-{aqua[1,3-bis-(penta-fluoro-phen-yl)propane-1,3-dionato-K 2 O,O′]nickel(II)} benzene tetra-solvate

AU - Hori, Akiko

AU - Mizutani, Masaya

PY - 2009

Y1 - 2009

N2 - The title complex comprises two Ni2+ ions, four fluorinated ligands and two water mol-ecules in a centrosymmetric dinuclear complex. This compound was crystallized from benzene-CH2Cl2, and two types of crystals, viz. the title benzene tetra-solvate, [Ni2(C 15HF10O2)4(H2O) 2]·4C6H6, (I), and the previously reported benzene disolvate, [Ni2(C15HF10O 2)4(H2O)2]·2C 6H6, (II) [Hori et al. (2009). Bull. Chem. Soc. Jpn, 82, 96-98], were obtained as pseudopolymorphs. In the crystal structure of (I), the four benzene solvent mol-ecules inter-act closely with all the penta-fluoro-phenyl groups of the complex through arene-perfluoro-arene inter-actions. The mol-ecular structures of the two compounds show essentially the same conformation, although the benzene mol-ecules are accommodated in a columnar packing in (I), while they are isolated from each other in (II).

AB - The title complex comprises two Ni2+ ions, four fluorinated ligands and two water mol-ecules in a centrosymmetric dinuclear complex. This compound was crystallized from benzene-CH2Cl2, and two types of crystals, viz. the title benzene tetra-solvate, [Ni2(C 15HF10O2)4(H2O) 2]·4C6H6, (I), and the previously reported benzene disolvate, [Ni2(C15HF10O 2)4(H2O)2]·2C 6H6, (II) [Hori et al. (2009). Bull. Chem. Soc. Jpn, 82, 96-98], were obtained as pseudopolymorphs. In the crystal structure of (I), the four benzene solvent mol-ecules inter-act closely with all the penta-fluoro-phenyl groups of the complex through arene-perfluoro-arene inter-actions. The mol-ecular structures of the two compounds show essentially the same conformation, although the benzene mol-ecules are accommodated in a columnar packing in (I), while they are isolated from each other in (II).

UR - http://www.scopus.com/inward/record.url?scp=70449379939&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=70449379939&partnerID=8YFLogxK

U2 - 10.1107/S0108270109037184

DO - 10.1107/S0108270109037184

M3 - Article

C2 - 19893222

AN - SCOPUS:70449379939

VL - 65

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 11

ER -