A new oxychloride, Ba2CuO2Cl2, prepared under high pressure

T. Tatsuki, A. Tokiwa-Yamamoto, T. Tamura, Y. Moriwaki, X. J. Wu, S. Adachi, K. Tanabe

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Abstract

We synthesized a new copper-oxychloride, Ba2CuO2Cl2, from BaCl2, BaO2 and Cu-metal powders under a high pressure of 6 GPa at 1000°C. X-ray powder diffraction and TEM observation indicated that Ba2CuO2Cl2 crystallizes in a tetragonal K2NiF4 structure with lattice parameters of a = 4.1026(3) Å and c = 16.442(1) Å. It was found from iodometric titration and SEM-EDX analysis that the average valence of the Cu ions is +1.8 and 10% chlorine is deficient.

Original languageEnglish
Pages (from-to)323-327
Number of pages5
JournalPhysica C: Superconductivity and its applications
Volume265
Issue number3-4
DOIs
Publication statusPublished - 1996 Jul 10

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ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Energy Engineering and Power Technology
  • Electrical and Electronic Engineering

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