A stable lithium-rich surface structure for lithium-rich layered cathode materials

Sangryun Kim, Woosuk Cho, Xiaobin Zhang, Yoshifumi Oshima, Jang Wook Choi

Research output: Contribution to journalArticle

56 Citations (Scopus)

Abstract

Lithium ion batteries are encountering ever-growing demand for further increases in energy density. Li-rich layered oxides are considered a feasible solution to meet this demand because their specific capacities often surpass 200 mAh g -1 due to the additional lithium occupation in the transition metal layers. However, this lithium arrangement, in turn, triggers cation mixing with the transition metals, causing phase transitions during cycling and loss of reversible capacity. Here we report a Li-rich layered surface bearing a consistent framework with the host, in which nickel is regularly arranged between the transition metal layers. This surface structure mitigates unwanted phase transitions, improving the cycling stability. This surface modification enables a reversible capacity of 218.3 mAh g -1 at 1C (250 mA g -1 ) with improved cycle retention (94.1% after 100 cycles). The present surface design can be applied to various battery electrodes that suffer from structural degradations propagating from the surface.

Original languageEnglish
Article number13598
JournalNature Communications
Volume7
DOIs
Publication statusPublished - 2016 Nov 25
Externally publishedYes

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Lithium
Surface structure
Transition metals
Cathodes
lithium
cathodes
Bearings (structural)
Phase transitions
cycles
transition metals
electric batteries
Nickel
Oxides
Surface treatment
Cations
Degradation
Electrodes
occupation
flux density
actuators

ASJC Scopus subject areas

  • Chemistry(all)
  • Biochemistry, Genetics and Molecular Biology(all)
  • Physics and Astronomy(all)

Cite this

A stable lithium-rich surface structure for lithium-rich layered cathode materials. / Kim, Sangryun; Cho, Woosuk; Zhang, Xiaobin; Oshima, Yoshifumi; Choi, Jang Wook.

In: Nature Communications, Vol. 7, 13598, 25.11.2016.

Research output: Contribution to journalArticle

Kim, Sangryun ; Cho, Woosuk ; Zhang, Xiaobin ; Oshima, Yoshifumi ; Choi, Jang Wook. / A stable lithium-rich surface structure for lithium-rich layered cathode materials. In: Nature Communications. 2016 ; Vol. 7.
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