An electrolytic system based on the anion exchange reaction between KCl and an anion exchange resin

Atsushi Nakajima, Toshiki Tajima

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

We have developed a novel electrolytic system based on the anion exchange reaction between KCl and Amberlyst A26. It was demonstrated by preparative electrolysis experiments as well as cyclic voltammetry that the anion exchange reaction offers a unique electrolytic system for electroreduction of organic compounds. On the basis of the electrolytic system, electroreduction of aromatic carbonyl compounds was successfully achieved by using an undivided cell to provide the corresponding coupling products as pinacols in good to high yields with high diastereoselectivity.

Original languageEnglish
Pages (from-to)1199-1202
Number of pages4
JournalElectrochemistry Communications
Volume11
Issue number6
DOIs
Publication statusPublished - 2009 Jun
Externally publishedYes

Fingerprint

Anion Exchange Resins
Anions
Ion exchange
Negative ions
Resins
Carbonyl compounds
Electrolysis
Organic compounds
Cyclic voltammetry
Experiments

Keywords

  • Anion exchange reaction
  • Anion exchange resin
  • Electroreduction
  • Potassium chloride
  • Supporting electrolyte

ASJC Scopus subject areas

  • Electrochemistry

Cite this

An electrolytic system based on the anion exchange reaction between KCl and an anion exchange resin. / Nakajima, Atsushi; Tajima, Toshiki.

In: Electrochemistry Communications, Vol. 11, No. 6, 06.2009, p. 1199-1202.

Research output: Contribution to journalArticle

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