An electrolytic system that uses solid-supported bases for in situ generation of a supporting electrolyte from acetic acid solvent

Toshiki Tajima, Toshio Fuchigami

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

Re-usability is trumps: The electrolytic system presented here (see graphic) has been used for the anodic acetoxylation of various compounds to provide the corresponding acetoxylated products in good to excellent yields. The acetoxylated products and the solid-supported bases can easily be separated by filtration, and the separated solid-supported bases can be re-used many times. (Chemical Equation Presented)

Original languageEnglish
Pages (from-to)4760-4763
Number of pages4
JournalAngewandte Chemie - International Edition
Volume44
Issue number30
DOIs
Publication statusPublished - 2005 Jul 25
Externally publishedYes

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Acetic acid
Acetic Acid
Electrolytes
Reusability

Keywords

  • Acetoxylation
  • Electrochemistry
  • Electroorganic synthesis
  • Green chemistry
  • Solid-supported base

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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AB - Re-usability is trumps: The electrolytic system presented here (see graphic) has been used for the anodic acetoxylation of various compounds to provide the corresponding acetoxylated products in good to excellent yields. The acetoxylated products and the solid-supported bases can easily be separated by filtration, and the separated solid-supported bases can be re-used many times. (Chemical Equation Presented)

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KW - Electrochemistry

KW - Electroorganic synthesis

KW - Green chemistry

KW - Solid-supported base

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