Anaerobic reduction of anthracycline antibiotics and their model compounds by FE(II) complexes

Masahiko Tachibana; Shozo Tero-kubota; Masamoto Iwaizumi

doi:10.1080/00958978808080690

Anaerobic reduction of anthracycline antibiotics and their model compounds by FE(II) complexes

Masahiko Tachibana, Shozo Tero-kubota, Masamoto Iwaizumi

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Hydroxyanthraquinones, model compounds for anthra- cycline antibiotics, are reduced by Fe(II)-ADP and Fe(II)- phosphate complexes to produce semiquinone radicals. In case the corresponding hydroquinone is stable, two electron reduction is caused by the Fe(II)-phosphate complex, rather strong reducing agent.

Original language	English
Pages (from-to)	77-84
Number of pages	8
Journal	Journal of Coordination Chemistry
Volume	18
Issue number	1-3
DOIs	https://doi.org/10.1080/00958978808080690
Publication status	Published - 1988 Sep 1
Externally published	Yes

Keywords

Hydroxyanthraquinones
semiquinone radicals

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Materials Chemistry

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10.1080/00958978808080690

Cite this

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abstract = "Hydroxyanthraquinones, model compounds for anthra- cycline antibiotics, are reduced by Fe(II)-ADP and Fe(II)- phosphate complexes to produce semiquinone radicals. In case the corresponding hydroquinone is stable, two electron reduction is caused by the Fe(II)-phosphate complex, rather strong reducing agent.",

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AU - Iwaizumi, Masamoto

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Y1 - 1988/9/1

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AB - Hydroxyanthraquinones, model compounds for anthra- cycline antibiotics, are reduced by Fe(II)-ADP and Fe(II)- phosphate complexes to produce semiquinone radicals. In case the corresponding hydroquinone is stable, two electron reduction is caused by the Fe(II)-phosphate complex, rather strong reducing agent.

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KW - semiquinone radicals

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Anaerobic reduction of anthracycline antibiotics and their model compounds by FE(II) complexes

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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