Abstract
Anodic fluorination of toluene, ethylbenzene, and cumene derivatives was comparatively studied using Et4NF-4HF as a supporting electrolyte and a fluorine source. Anodic benzylic fluorination occurred except for some cumene derivatives and the yields of the fluorinated products greatly depended on the stability of benzylic cations.
| Original language | English |
|---|---|
| Pages (from-to) | 589-592 |
| Number of pages | 4 |
| Journal | Electrochemistry Communications |
| Volume | 4 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - 2002 |
| Externally published | Yes |
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Keywords
- Anodic benzylic fluorination
- Electron-donating group
- Electron-withdrawing group
- Oxidation potential
- Stability of benzylic cation
ASJC Scopus subject areas
- Chemical Engineering(all)
- Analytical Chemistry
- Electrochemistry
Cite this
Anodic benzylic fluorination of toluene, ethylbenzene, and cumene derivatives. / Tajima, Toshiki; Ishii, Hideki; Fuchigami, Toshio.
In: Electrochemistry Communications, Vol. 4, No. 7, 2002, p. 589-592.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Anodic benzylic fluorination of toluene, ethylbenzene, and cumene derivatives
AU - Tajima, Toshiki
AU - Ishii, Hideki
AU - Fuchigami, Toshio
PY - 2002
Y1 - 2002
N2 - Anodic fluorination of toluene, ethylbenzene, and cumene derivatives was comparatively studied using Et4NF-4HF as a supporting electrolyte and a fluorine source. Anodic benzylic fluorination occurred except for some cumene derivatives and the yields of the fluorinated products greatly depended on the stability of benzylic cations.
AB - Anodic fluorination of toluene, ethylbenzene, and cumene derivatives was comparatively studied using Et4NF-4HF as a supporting electrolyte and a fluorine source. Anodic benzylic fluorination occurred except for some cumene derivatives and the yields of the fluorinated products greatly depended on the stability of benzylic cations.
KW - Anodic benzylic fluorination
KW - Electron-donating group
KW - Electron-withdrawing group
KW - Oxidation potential
KW - Stability of benzylic cation
UR - http://www.scopus.com/inward/record.url?scp=0036315908&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0036315908&partnerID=8YFLogxK
U2 - 10.1016/S1388-2481(02)00381-8
DO - 10.1016/S1388-2481(02)00381-8
M3 - Article
AN - SCOPUS:0036315908
VL - 4
SP - 589
EP - 592
JO - Electrochemistry Communications
JF - Electrochemistry Communications
SN - 1388-2481
IS - 7
ER -