Anodic fluorination based on cation exchange between alkali-metal fluorides and solid-supported acids

Toshiki Tajima, Atsushi Nakajima, Yuta Doi, Toshio Fuchigami

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

(Chemical Equation Presented) Positively shocking: The interchange of cations between alkali-metal fluorides and solid-supported acids (see picture) in an electrolytic system promotes the anodic fluorination of organic compounds to give the corresponding fluorinated products in good to excellent yields.

Original languageEnglish
Pages (from-to)3550-3552
Number of pages3
JournalAngewandte Chemie - International Edition
Volume46
Issue number19
DOIs
Publication statusPublished - 2007
Externally publishedYes

Fingerprint

Alkali Metals
Fluorination
Interchanges
Alkali metals
Fluorides
Organic compounds
Cations
Ion exchange
Positive ions
Acids

Keywords

  • Alkali metals
  • Cation exchange
  • Electrochemistry
  • Fluorides
  • Ion pairs

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Anodic fluorination based on cation exchange between alkali-metal fluorides and solid-supported acids. / Tajima, Toshiki; Nakajima, Atsushi; Doi, Yuta; Fuchigami, Toshio.

In: Angewandte Chemie - International Edition, Vol. 46, No. 19, 2007, p. 3550-3552.

Research output: Contribution to journalArticle

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