Ar-plasma-modulated optical reset in the SiO2/Cu conductive-bridge resistive memory stack

T. Kawashima, K. S. Yew, Y. Zhou, D. S. Ang, H. Z. Zhang, Kentaro Kyuno

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Our study using conductive atomic force microscope shows that the resistive switching voltage in the SiO2/Cu stack is reduced by 33% after Ar plasma treatment of the oxide. Besides, the negative photo-conductivity (NPC) effect, normally observed on many locations following electrical soft-breakdown, is suppressed. The NPC effect arises because the electrically-formed filamentary conductive path, comprising both Cu and oxygen vacancies, may be disrupted by the recombination of the vacancies with nearby light-excited interstitial oxygen ions. Increase of the O-H peak, as seen from FT-IR spectroscopy, indicates that surface defects generated by the Ar plasma may have adsorbed water molecules, which in turn act as counter anions (OH-) accelerating Cu-ion diffusion into the oxide, forming a more complete Cu Filament that is non-responsive to light. The finding offers the possibility of both electrical and optical resistance control by a simple surface treatment step.

Original languageEnglish
Title of host publicationECS Transactions
EditorsB. Magyari-Kope, G. Bersuker, K. Kobayashi, C. Hacker, J.G. Park, S. Shingubara, Y. Saito, Z. Karim, H. Shima, H. Kubota, Y.S. Obeng
PublisherElectrochemical Society Inc.
Pages55-64
Number of pages10
Volume86
Edition3
ISBN (Electronic)9781607685395
DOIs
Publication statusPublished - 2018 Jan 1
EventSymposium on Nonvolatile Memories 6 and Surface Characterization and Manipulation for Electronic Applications - AiMES 2018, ECS and SMEQ Joint International Meeting - Cancun, Mexico
Duration: 2018 Sep 302018 Oct 4

Other

OtherSymposium on Nonvolatile Memories 6 and Surface Characterization and Manipulation for Electronic Applications - AiMES 2018, ECS and SMEQ Joint International Meeting
CountryMexico
CityCancun
Period18/9/3018/10/4

ASJC Scopus subject areas

  • Engineering(all)

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    Kawashima, T., Yew, K. S., Zhou, Y., Ang, D. S., Zhang, H. Z., & Kyuno, K. (2018). Ar-plasma-modulated optical reset in the SiO2/Cu conductive-bridge resistive memory stack. In B. Magyari-Kope, G. Bersuker, K. Kobayashi, C. Hacker, J. G. Park, S. Shingubara, Y. Saito, Z. Karim, H. Shima, H. Kubota, & Y. S. Obeng (Eds.), ECS Transactions (3 ed., Vol. 86, pp. 55-64). Electrochemical Society Inc.. https://doi.org/10.1149/08603.0055ecst