TY - JOUR
T1 - Asymmetric forward osmosis membranes from p-aramid nanofibers
AU - Miao, Lei
AU - Jiang, Tingting
AU - Lin, Shudong
AU - Jin, Tao
AU - Hu, Jiwen
AU - Zhang, Min
AU - Tu, Yuanyuan
AU - Liu, Guojun
N1 - Funding Information:
Dr. Jiwen Hu wishes to thank the National Natural Science Foundation of China , China (No. 51173204 , 21404121 , and 51503124 ), the Pearl River Novel Science and Technology Project of Guangzhou , China (No. 201506010031 ), the Development Fund for Special Strategic Emerging Industry in Guangdong Province , China ( 2015B090915004 ), the Guangdong Natural Science Foundation , China ( 2015A030313799 , 2015A030313822 and 2016A030313163 ), the Science and Technology Program of Guangzhou City , China ( 201510010128 ), the Science Research Special Project of Guangzhou City , China ( 2014J4100216 ), and the Production Education Research Project in Guangdong Province , China ( 2015B090915004 , 2015B010135002 ) for providing financial support. Dr. L. Miao wishes to thank the Foshan Functional Polymer Engineering Center , China (No. 2016GA10162 ), the key Project of the Department of Education of Guangdong Province , China (No. 2016GCZX008 ), and the Guangdong Natural Science Foundation , China (No. 2018A030313717 , 2014A030310426 ) for providing support. Dr. Ian Wyman is thanked for proofreading this manuscript.
Funding Information:
Dr. Jiwen Hu wishes to thank the National Natural Science Foundation of China, China (No. 51173204, 21404121, and 51503124), the Pearl River Novel Science and Technology Project of Guangzhou, China (No. 201506010031), the Development Fund for Special Strategic Emerging Industry in Guangdong Province, China (2015B090915004), the Guangdong Natural Science Foundation, China (2015A030313799, 2015A030313822 and 2016A030313163), the Science and Technology Program of Guangzhou City, China (201510010128), the Science Research Special Project of Guangzhou City, China (2014J4100216), and the Production Education Research Project in Guangdong Province, China (2015B090915004, 2015B010135002) for providing financial support. Dr. L. Miao wishes to thank the Foshan Functional Polymer Engineering Center, China (No. 2016GA10162), the key Project of the Department of Education of Guangdong Province, China (No. 2016GCZX008), and the Guangdong Natural Science Foundation, China (No. 2018A030313717, 2014A030310426) for providing support. Dr. Ian Wyman is thanked for proofreading this manuscript.
Publisher Copyright:
© 2020 The Authors
PY - 2020/6
Y1 - 2020/6
N2 - p-Aramid is an ideal building block for forward osmosis (FO) membranes due to its extraordinary thermal resistance, chemical stability, and mechanical properties. However, existing aramid membranes have certain limitations such as large pore diameters and low salt rejection rates. In this work, we describe a facile solvent exchange-delay phase inversion strategy to prepare p-aramid nanofibrous membranes that would be suitable for FO applications. In this strategy, p-aramid nanofibers with an average diameter of 16 ± 4 nm and an average length of 382 ± 89 nm were employed as membrane matrices. Prior to the immersion of the cast film into a coagulation bath, a pre-evaporation protocol was carefully designed and introduced to provide a slower exchange rate between the good solvent and the non-solvent, which delayed the demixing process between p-aramid nanofibers and thus yielded an asymmetric membrane with a denser active layer as well as a loose substrate layer. The resultant membrane showed excellent FO water flux, NaCl rejection ratios, tensile strength, thermal properties, and solvent resistance. The membrane reported in this work may provide a promising candidate for separation applications and the results reported herein will facilitate the development of high-performance nanofibrous membranes.
AB - p-Aramid is an ideal building block for forward osmosis (FO) membranes due to its extraordinary thermal resistance, chemical stability, and mechanical properties. However, existing aramid membranes have certain limitations such as large pore diameters and low salt rejection rates. In this work, we describe a facile solvent exchange-delay phase inversion strategy to prepare p-aramid nanofibrous membranes that would be suitable for FO applications. In this strategy, p-aramid nanofibers with an average diameter of 16 ± 4 nm and an average length of 382 ± 89 nm were employed as membrane matrices. Prior to the immersion of the cast film into a coagulation bath, a pre-evaporation protocol was carefully designed and introduced to provide a slower exchange rate between the good solvent and the non-solvent, which delayed the demixing process between p-aramid nanofibers and thus yielded an asymmetric membrane with a denser active layer as well as a loose substrate layer. The resultant membrane showed excellent FO water flux, NaCl rejection ratios, tensile strength, thermal properties, and solvent resistance. The membrane reported in this work may provide a promising candidate for separation applications and the results reported herein will facilitate the development of high-performance nanofibrous membranes.
KW - Forward osmosis membranes
KW - Phase inversion
KW - p-Aramid nanofibers
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U2 - 10.1016/j.matdes.2020.108591
DO - 10.1016/j.matdes.2020.108591
M3 - Article
AN - SCOPUS:85080086498
VL - 191
JO - International Journal of Materials in Engineering Applications
JF - International Journal of Materials in Engineering Applications
SN - 0264-1275
M1 - 108591
ER -