Beckmann rearrangement of O-4-pentenyl oxime through N- bromosuccinimide-mediated activating process

Osamu Kitagawa; Masao Fujita; Midori Okada; Takeo Taguchi

doi:10.1248/cpb.45.32

Beckmann rearrangement of O-4-pentenyl oxime through N- bromosuccinimide-mediated activating process

Osamu Kitagawa, Masao Fujita, Midori Okada, Takeo Taguchi

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Beckmann rearrangement of O-4-pentenyl oxime derivatives proceeds in good yield under mild conditions through the formation of a cationic tetrahydrofuranium intermediate in the halocyclization reaction with N- bromosuccinimide.

Original language	English
Pages (from-to)	32-35
Number of pages	4
Journal	Chemical and Pharmaceutical Bulletin
Volume	45
Issue number	1
DOIs	https://doi.org/10.1248/cpb.45.32
Publication status	Published - 1997 Jan
Externally published	Yes

Keywords

Beckmann rearrangement
N- bromosuccinimide
O-4-pentenyl oxime
halocyclization
tetrahydrofuranium

ASJC Scopus subject areas

Chemistry(all)
Drug Discovery

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title = "Beckmann rearrangement of O-4-pentenyl oxime through N- bromosuccinimide-mediated activating process",

abstract = "Beckmann rearrangement of O-4-pentenyl oxime derivatives proceeds in good yield under mild conditions through the formation of a cationic tetrahydrofuranium intermediate in the halocyclization reaction with N- bromosuccinimide.",

keywords = "Beckmann rearrangement, N- bromosuccinimide, O-4-pentenyl oxime, halocyclization, tetrahydrofuranium",

author = "Osamu Kitagawa and Masao Fujita and Midori Okada and Takeo Taguchi",

year = "1997",

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doi = "10.1248/cpb.45.32",

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AU - Kitagawa, Osamu

AU - Fujita, Masao

AU - Okada, Midori

AU - Taguchi, Takeo

PY - 1997/1

Y1 - 1997/1

N2 - Beckmann rearrangement of O-4-pentenyl oxime derivatives proceeds in good yield under mild conditions through the formation of a cationic tetrahydrofuranium intermediate in the halocyclization reaction with N- bromosuccinimide.

AB - Beckmann rearrangement of O-4-pentenyl oxime derivatives proceeds in good yield under mild conditions through the formation of a cationic tetrahydrofuranium intermediate in the halocyclization reaction with N- bromosuccinimide.

KW - Beckmann rearrangement

KW - N- bromosuccinimide

KW - O-4-pentenyl oxime

KW - halocyclization

KW - tetrahydrofuranium

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