Behavior of Mg2Ni hydrogen-absorbing alloy in an alkaline solution

Hiroaki Nakano, Toshiro Kuji, Tatsuhiko Aizawa

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Two specific phenomena were observed during electrochemical charging and discharging processes for Mg2Ni alloy electrode at the first cycle, i.e., the decrease of the absorbed hydrogen content (difference between the charged quantity of electricity and the hydrogen gas volume converted to the quantity of electricity) in an alloy during charging process and the discharge capacity larger than the absorbed hydrogen content. In order to investigate these phenomena, the electrochemical behavior of Mg2Ni alloy powders prepared by casting and bulk mechanical alloying(BMA) was studied in 6M KOH solution and water. It was consequently found that Mg(OH)2 was formed and at the same time atomic hydrogen was also formed in the solution so that the hydrogen was absorbed into Mg2Ni alloy. Hydrogen gas was also generated from the alloy surface after hydrogen absorbed was almost saturated in the alloy. Consequently, it was clearly concluded that the specific phenomenon of the former is due to the generation of gaseous hydrogen when Mg2Ni alloy reacted with H2O. The latter is also because of the discharge of the hydrogen absorbed into Mg2Ni by forming Mg(OH)2, except for discharge of the hydrogen absorbed electrochemically.

Original languageEnglish
Pages (from-to)259-263
Number of pages5
JournalElectrochemistry
Volume69
Issue number4
Publication statusPublished - 2001 Apr
Externally publishedYes

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Hydrogen
Electricity
Gases
Mechanical alloying
Powders
Casting
Electrodes
Water

Keywords

  • Behavior in Alkaline Solution
  • Corrosion of Magnesium
  • Magnesium-Nickel Alloy
  • Metal Hydride Electrode

ASJC Scopus subject areas

  • Electrochemistry

Cite this

Nakano, H., Kuji, T., & Aizawa, T. (2001). Behavior of Mg2Ni hydrogen-absorbing alloy in an alkaline solution. Electrochemistry, 69(4), 259-263.

Behavior of Mg2Ni hydrogen-absorbing alloy in an alkaline solution. / Nakano, Hiroaki; Kuji, Toshiro; Aizawa, Tatsuhiko.

In: Electrochemistry, Vol. 69, No. 4, 04.2001, p. 259-263.

Research output: Contribution to journalArticle

Nakano, H, Kuji, T & Aizawa, T 2001, 'Behavior of Mg2Ni hydrogen-absorbing alloy in an alkaline solution', Electrochemistry, vol. 69, no. 4, pp. 259-263.
Nakano H, Kuji T, Aizawa T. Behavior of Mg2Ni hydrogen-absorbing alloy in an alkaline solution. Electrochemistry. 2001 Apr;69(4):259-263.
Nakano, Hiroaki ; Kuji, Toshiro ; Aizawa, Tatsuhiko. / Behavior of Mg2Ni hydrogen-absorbing alloy in an alkaline solution. In: Electrochemistry. 2001 ; Vol. 69, No. 4. pp. 259-263.
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