Bismuth(III) triflate-catalyzed dehydrative glycosidation using 1-hydroxy sugars

Takashi Yamanoi, Ryo Inoue, Sho Matsuda, Keita Hamasaki

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

This paper describes the O-glycoside formation from 1-hydroxy sugars by the bismuth(III) triflate-catalyzed dehydrative glycosidation. The reactions of the 1-hydroxy sugars with some primary alcohols in the presence of only 5 mol% bismuth(III) triflate at reflux for 15 min in dichloromethane afforded the O-glycosides in good yields. This paper clarifies several important properties during the bismuth(III) triflate-catalyzed dehydrative glycosidation using 1-hydroxy sugars.

Original languageEnglish
Pages (from-to)30-33
Number of pages4
JournalLetters in Organic Chemistry
Volume5
Issue number1
DOIs
Publication statusPublished - 2008 Jan 1

Keywords

  • 1,1'-disaccharide
  • 1-hydroxy sugar
  • Bismuth(III) triflate
  • Glycosidation
  • Glycoside

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry

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