Blue/red linear dichroic emission from a highly anisotropic crystal of triarylmethane dye conjugated with phenoxo-zinc complexes

Hirohiko Houjou, Shunpei Takezawa, Issei Oyamada, Kazunari Matsumura, Hidetake Seino, Isao Yoshikawa, Yasushi Mizobe, Koji Araki

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We have developed a novel triphenylmethane-based hexanuclear zinc complex that exhibits peculiar photochemical and photophysical properties. Upon UV irradiation, the compound turned from colorless to reddish purple, while the color of emission turned from blue to red. The color change was attributed to an oxidation of the ligand part. It was suggested that an intramolecular energy-transfer mechanism operates to give rise to the red emission. The UV treatment of a single crystal results in simultaneous emission of orthogonally polarized blue and red light. This color switching, namely linear dichroic emission was so distinct that one can recognize with by sight through optical microscope. The columnar arrangement of molecules in the crystal clearly accounts for the observed polarization of the emission.

Original languageEnglish
Pages (from-to)1122-1127
Number of pages6
JournalChemistry - A European Journal
Issue number4
Publication statusPublished - 2011 Jan 24



  • crystal engineering
  • energy transfer
  • luminescence
  • polarized emission
  • transition metals

ASJC Scopus subject areas

  • Chemistry(all)

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