Bubble-free System for Belousov-Zhabotinsky Gels

Yuji Otsuka, Yuto Sato, Shingo Maeda

Research output: Contribution to journalArticle

Abstract

The chemical energy from the Belousov-Zhabotinsky (BZ) reaction powers autonomous mechanical oscillations in BZ gels. One drawback is that the process produces carbon dioxide bubbles, making lengthy experiments and practical applications difficult. Herein we synthesize a microphase-separated BZ gel and determine mechanical oscillation conditions that do not generate bubbles. Investigations of the thermodynamic mechanism of the CHD-BZ gel using 1,4-cyclohexanedione (CHD) reveals that the Flory interaction parameter » is altered by the redox changes to the metal ion incorporated in a microphaseseparated CHD-BZ gel. This microphase-separated structure leads to alterations in » as well as the entropy when redox changes occur in a microphase-separated CHD-BZ gel.

Original languageEnglish
Pages (from-to)863-866
Number of pages4
JournalChemistry Letters
Volume49
Issue number7
DOIs
Publication statusPublished - 2020 Jul

Keywords

  • Belousov-zhabotinsky reaction
  • Chemical oscillation
  • Hydrogels

ASJC Scopus subject areas

  • Chemistry(all)

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