Chiral initiator-induces self-disproportionation of enantiomers via achiral chromatography: Application to enantiomer separation of racemate

Kaori Tateishi; Shiori Tsukagoshi; Tsuyoshi Nakamura; Shotaro Watanabe; Vadim A. Soloshonok; Osamu Kitagawa

doi:10.1016/j.tetlet.2013.07.061

Chiral initiator-induces self-disproportionation of enantiomers via achiral chromatography: Application to enantiomer separation of racemate

Kaori Tateishi, Shiori Tsukagoshi, Tsuyoshi Nakamura, Shotaro Watanabe, Vadim A. Soloshonok, Osamu Kitagawa

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

We report here the theoretical design and proof of principle of the first example of a conceptually new approach for the preparation of enantiomerically pure compounds from the racemates by chiral initiator-induced Self-Disproportionation of Enantiomers (SDE) via achiral chromatography.

Original language	English
Pages (from-to)	5220-5223
Number of pages	4
Journal	Tetrahedron Letters
Volume	54
Issue number	38
DOIs	https://doi.org/10.1016/j.tetlet.2013.07.061
Publication status	Published - 2013 Sept 18

Keywords

Association
Chromatography
Disproportionation
Enantiomers
Optical resolution

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2013.07.061

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keywords = "Association, Chromatography, Disproportionation, Enantiomers, Optical resolution",

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AU - Tateishi, Kaori

AU - Tsukagoshi, Shiori

AU - Nakamura, Tsuyoshi

AU - Watanabe, Shotaro

AU - Soloshonok, Vadim A.

AU - Kitagawa, Osamu

PY - 2013/9/18

Y1 - 2013/9/18

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KW - Chromatography

KW - Disproportionation

KW - Enantiomers

KW - Optical resolution

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Chiral initiator-induces self-disproportionation of enantiomers via achiral chromatography: Application to enantiomer separation of racemate

Abstract

Keywords

ASJC Scopus subject areas

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