Chirality-dependent halogen bonds in axially chiral quinazolin-4-one derivatives bearing: Ortho -halophenyl groups

Tomomi Imai, Erina Niijima, Shumpei Terada, Alicja Wzorek, Vadim A. Soloshonok, Akiko Hori, Osamu Kitagawa

Research output: Contribution to journalArticlepeer-review

Abstract

In the crystals prepared from racemic axially chiral 3-(ortho-halophenyl)-2-methylquinazolin-4-one derivatives, the formation of intermolecular halogen bonding (CO⋯X) between the carbonyl oxygen and ortho-halogen atom (X = Cl, Br, I) was found, while in the crystals prepared from their optically pure forms, such halogen bonding was not detected.

Original languageEnglish
Pages (from-to)3385-3389
Number of pages5
JournalCrystEngComm
Volume21
Issue number22
DOIs
Publication statusPublished - 2019 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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