Chirality-dependent halogen bonds in axially chiral quinazolin-4-one derivatives bearing: Ortho -halophenyl groups

Tomomi Imai, Erina Niijima, Shumpei Terada, Alicja Wzorek, Vadim A. Soloshonok, Akiko Hori, Osamu Kitagawa

Research output: Contribution to journalArticle

Abstract

In the crystals prepared from racemic axially chiral 3-(ortho-halophenyl)-2-methylquinazolin-4-one derivatives, the formation of intermolecular halogen bonding (CO⋯X) between the carbonyl oxygen and ortho-halogen atom (X = Cl, Br, I) was found, while in the crystals prepared from their optically pure forms, such halogen bonding was not detected.

Original languageEnglish
Pages (from-to)3385-3389
Number of pages5
JournalCrystEngComm
Volume21
Issue number22
DOIs
Publication statusPublished - 2019 Jan 1

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Bearings (structural)
Halogens
Chirality
chirality
halogens
Derivatives
Crystals
Atoms
crystals
Oxygen
oxygen
atoms
4-hydroxyquinazoline

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Chirality-dependent halogen bonds in axially chiral quinazolin-4-one derivatives bearing : Ortho -halophenyl groups. / Imai, Tomomi; Niijima, Erina; Terada, Shumpei; Wzorek, Alicja; Soloshonok, Vadim A.; Hori, Akiko; Kitagawa, Osamu.

In: CrystEngComm, Vol. 21, No. 22, 01.01.2019, p. 3385-3389.

Research output: Contribution to journalArticle

Imai, Tomomi ; Niijima, Erina ; Terada, Shumpei ; Wzorek, Alicja ; Soloshonok, Vadim A. ; Hori, Akiko ; Kitagawa, Osamu. / Chirality-dependent halogen bonds in axially chiral quinazolin-4-one derivatives bearing : Ortho -halophenyl groups. In: CrystEngComm. 2019 ; Vol. 21, No. 22. pp. 3385-3389.
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