Chirality induction through the reversible catenation of coordination rings

Akiko Hori, Akihiko Akasaka, Kumar Biradha, Shigeru Sakamoto, Kentaro Yamaguchi, Makoto Fujita

Research output: Contribution to journal › Article

55 Citations (Scopus)

Abstract

Switching on chirality: Reversible catenation allows switching between achiral, planar, PdII-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.

Original languageEnglish
Pages (from-to)3269-3272
Number of pages4
JournalAngewandte Chemie - International Edition
Volume41
Issue number17
DOIs
Publication statusPublished - 2002 Sep 2
Externally publishedYes

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Chirality
Conformations
Metals
catenane

Keywords

  • Catenanes
  • Chirality
  • Helical structures
  • Palladium
  • Self-assembly

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Chirality induction through the reversible catenation of coordination rings. / Hori, Akiko; Akasaka, Akihiko; Biradha, Kumar; Sakamoto, Shigeru; Yamaguchi, Kentaro; Fujita, Makoto.

In: Angewandte Chemie - International Edition, Vol. 41, No. 17, 02.09.2002, p. 3269-3272.

Research output: Contribution to journal › Article

Hori, A, Akasaka, A, Biradha, K, Sakamoto, S, Yamaguchi, K & Fujita, M 2002, 'Chirality induction through the reversible catenation of coordination rings', Angewandte Chemie - International Edition, vol. 41, no. 17, pp. 3269-3272. https://doi.org/10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9
Hori A, Akasaka A, Biradha K, Sakamoto S, Yamaguchi K, Fujita M. Chirality induction through the reversible catenation of coordination rings. Angewandte Chemie - International Edition. 2002 Sep 2;41(17):3269-3272. https://doi.org/10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9
Hori, Akiko ; Akasaka, Akihiko ; Biradha, Kumar ; Sakamoto, Shigeru ; Yamaguchi, Kentaro ; Fujita, Makoto. / Chirality induction through the reversible catenation of coordination rings. In: Angewandte Chemie - International Edition. 2002 ; Vol. 41, No. 17. pp. 3269-3272.
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