Abstract
Switching on chirality: Reversible catenation allows switching between achiral, planar, PdII-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.
| Original language | English |
|---|---|
| Pages (from-to) | 3269-3272 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 41 |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - 2002 Sep 2 |
| Externally published | Yes |
Keywords
- Catenanes
- Chirality
- Helical structures
- Palladium
- Self-assembly
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Cite this
Hori, A., Akasaka, A., Biradha, K., Sakamoto, S., Yamaguchi, K., & Fujita, M. (2002). Chirality induction through the reversible catenation of coordination rings. Angewandte Chemie - International Edition, 41(17), 3269-3272. https://doi.org/10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9