Chirality induction through the reversible catenation of coordination rings

Akiko Hori; Akihiko Akasaka; Kumar Biradha; Shigeru Sakamoto; Kentaro Yamaguchi; Makoto Fujita

doi:10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9

Chirality induction through the reversible catenation of coordination rings

Akiko Hori, Akihiko Akasaka, Kumar Biradha, Shigeru Sakamoto, Kentaro Yamaguchi, Makoto Fujita

Research output: Contribution to journal › Article › peer-review

64 Citations (Scopus)

Abstract

Switching on chirality: Reversible catenation allows switching between achiral, planar, Pd^II-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.

Original language	English
Pages (from-to)	3269-3272
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	17
DOIs	https://doi.org/10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9
Publication status	Published - 2002 Sep 2
Externally published	Yes

Keywords

Catenanes
Chirality
Helical structures
Palladium
Self-assembly

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9

Cite this

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AU - Hori, Akiko

AU - Akasaka, Akihiko

AU - Biradha, Kumar

AU - Sakamoto, Shigeru

AU - Yamaguchi, Kentaro

AU - Fujita, Makoto

PY - 2002/9/2

Y1 - 2002/9/2

N2 - Switching on chirality: Reversible catenation allows switching between achiral, planar, PdII-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.

AB - Switching on chirality: Reversible catenation allows switching between achiral, planar, PdII-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.

KW - Catenanes

KW - Chirality

KW - Helical structures

KW - Palladium

KW - Self-assembly

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Chirality induction through the reversible catenation of coordination rings

Abstract

Keywords

ASJC Scopus subject areas

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