Chirality induction through the reversible catenation of coordination rings

Akiko Hori, Akihiko Akasaka, Kumar Biradha, Shigeru Sakamoto, Kentaro Yamaguchi, Makoto Fujita

Research output: Contribution to journalArticle

55 Citations (Scopus)

Abstract

Switching on chirality: Reversible catenation allows switching between achiral, planar, PdII-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.

Original languageEnglish
Pages (from-to)3269-3272
Number of pages4
JournalAngewandte Chemie - International Edition
Volume41
Issue number17
DOIs
Publication statusPublished - 2002 Sep 2
Externally publishedYes

Fingerprint

Chirality
Conformations
Metals
catenane

Keywords

  • Catenanes
  • Chirality
  • Helical structures
  • Palladium
  • Self-assembly

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Chirality induction through the reversible catenation of coordination rings. / Hori, Akiko; Akasaka, Akihiko; Biradha, Kumar; Sakamoto, Shigeru; Yamaguchi, Kentaro; Fujita, Makoto.

In: Angewandte Chemie - International Edition, Vol. 41, No. 17, 02.09.2002, p. 3269-3272.

Research output: Contribution to journalArticle

Hori, Akiko ; Akasaka, Akihiko ; Biradha, Kumar ; Sakamoto, Shigeru ; Yamaguchi, Kentaro ; Fujita, Makoto. / Chirality induction through the reversible catenation of coordination rings. In: Angewandte Chemie - International Edition. 2002 ; Vol. 41, No. 17. pp. 3269-3272.
@article{261ae33e56c54eddb2a9f7ebf51290de,
title = "Chirality induction through the reversible catenation of coordination rings",
abstract = "Switching on chirality: Reversible catenation allows switching between achiral, planar, PdII-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.",
keywords = "Catenanes, Chirality, Helical structures, Palladium, Self-assembly",
author = "Akiko Hori and Akihiko Akasaka and Kumar Biradha and Shigeru Sakamoto and Kentaro Yamaguchi and Makoto Fujita",
year = "2002",
month = "9",
day = "2",
doi = "10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9",
language = "English",
volume = "41",
pages = "3269--3272",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "17",

}

TY - JOUR

T1 - Chirality induction through the reversible catenation of coordination rings

AU - Hori, Akiko

AU - Akasaka, Akihiko

AU - Biradha, Kumar

AU - Sakamoto, Shigeru

AU - Yamaguchi, Kentaro

AU - Fujita, Makoto

PY - 2002/9/2

Y1 - 2002/9/2

N2 - Switching on chirality: Reversible catenation allows switching between achiral, planar, PdII-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.

AB - Switching on chirality: Reversible catenation allows switching between achiral, planar, PdII-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.

KW - Catenanes

KW - Chirality

KW - Helical structures

KW - Palladium

KW - Self-assembly

UR - http://www.scopus.com/inward/record.url?scp=0037008983&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037008983&partnerID=8YFLogxK

U2 - 10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9

DO - 10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9

M3 - Article

C2 - 12207412

AN - SCOPUS:0037008983

VL - 41

SP - 3269

EP - 3272

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 17

ER -