Abstract
Switching on chirality: Reversible catenation allows switching between achiral, planar, PdII-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.
| Original language | English |
|---|---|
| Pages (from-to) | 3269-3272 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 41 |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - 2002 Sep 2 |
| Externally published | Yes |
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Keywords
- Catenanes
- Chirality
- Helical structures
- Palladium
- Self-assembly
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Chirality induction through the reversible catenation of coordination rings. / Hori, Akiko; Akasaka, Akihiko; Biradha, Kumar; Sakamoto, Shigeru; Yamaguchi, Kentaro; Fujita, Makoto.
In: Angewandte Chemie - International Edition, Vol. 41, No. 17, 02.09.2002, p. 3269-3272.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Chirality induction through the reversible catenation of coordination rings
AU - Hori, Akiko
AU - Akasaka, Akihiko
AU - Biradha, Kumar
AU - Sakamoto, Shigeru
AU - Yamaguchi, Kentaro
AU - Fujita, Makoto
PY - 2002/9/2
Y1 - 2002/9/2
N2 - Switching on chirality: Reversible catenation allows switching between achiral, planar, PdII-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.
AB - Switching on chirality: Reversible catenation allows switching between achiral, planar, PdII-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.
KW - Catenanes
KW - Chirality
KW - Helical structures
KW - Palladium
KW - Self-assembly
UR - http://www.scopus.com/inward/record.url?scp=0037008983&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037008983&partnerID=8YFLogxK
U2 - 10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9
DO - 10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9
M3 - Article
C2 - 12207412
AN - SCOPUS:0037008983
VL - 41
SP - 3269
EP - 3272
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 17
ER -