Chirality induction through the reversible catenation of coordination rings

Akiko Hori; Akihiko Akasaka; Kumar Biradha; Shigeru Sakamoto; Kentaro Yamaguchi; Makoto Fujita

doi:10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9

Chirality induction through the reversible catenation of coordination rings

Akiko Hori, Akihiko Akasaka, Kumar Biradha, Shigeru Sakamoto, Kentaro Yamaguchi, Makoto Fujita

Research output: Contribution to journal › Article

57 Citations (Scopus)

Abstract

Switching on chirality: Reversible catenation allows switching between achiral, planar, Pd^II-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.

Original language	English
Pages (from-to)	3269-3272
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	17
DOIs	https://doi.org/10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9
Publication status	Published - 2002 Sep 2
Externally published	Yes

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Keywords

Catenanes
Chirality
Helical structures
Palladium
Self-assembly

ASJC Scopus subject areas

Chemistry(all)

Cite this

Hori, A., Akasaka, A., Biradha, K., Sakamoto, S., Yamaguchi, K., & Fujita, M. (2002). Chirality induction through the reversible catenation of coordination rings. Angewandte Chemie - International Edition, 41(17), 3269-3272. https://doi.org/10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9

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AU - Fujita, Makoto

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Access to Document

10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9