Chlorine adlayer-templated growth of a hybrid inorganic–organic layered structure on Au(111)

I. I. Rzeźnicka, H. Horino, K. Yagyu, T. Suzuki, S. Kajimoto, H. Fukumura

Research output: Contribution to journalArticle

Abstract

Growth of a hybrid inorganic–organic layered structure on the Au(111) surface using a one-step solution growth is reported. The hybrid structure is consist of 4,4′-bipyridine [4,4′-BiPyH2]2 + cations, Cl anions and Au adatoms, provided from substrate by means of the adsorbate-induced surface phase transition of a surface reconstruction. Its surface and bulk structures were characterized by scanning tunneling microscopy (STM), secondary ion mass spectrometry (SIMS), and Raman spectroscopy. STM results reveal growth of the first [4,4′-BiPyH2]2 + layer on top of the [Formula presented] chlorine overlayer formed on the Au(111) surface. These two layers are found to provide a platform for a following three-dimensional growth facilitated by hydrogen bonding, aurophilic and π–π stacking interactions.

LanguageEnglish
Pages46-50
Number of pages5
JournalSurface Science
Volume652
DOIs
StatePublished - 2016 Oct 1
Externally publishedYes

Fingerprint

Chlorine
chlorine
Scanning tunneling microscopy
scanning tunneling microscopy
Surface reconstruction
Adatoms
Adsorbates
Secondary ion mass spectrometry
hybrid structures
Anions
Raman spectroscopy
Cations
Hydrogen bonds
Negative ions
Phase transitions
Positive ions
secondary ion mass spectrometry
adatoms
platforms
anions

Keywords

  • Au(111)
  • Aurophilic interaction
  • Bipyridine
  • Chlorine overlayer
  • Scanning tunneling microscopy
  • Tip-enhanced Raman spectroscopy

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

Chlorine adlayer-templated growth of a hybrid inorganic–organic layered structure on Au(111). / Rzeźnicka, I. I.; Horino, H.; Yagyu, K.; Suzuki, T.; Kajimoto, S.; Fukumura, H.

In: Surface Science, Vol. 652, 01.10.2016, p. 46-50.

Research output: Contribution to journalArticle

Rzeźnicka II, Horino H, Yagyu K, Suzuki T, Kajimoto S, Fukumura H. Chlorine adlayer-templated growth of a hybrid inorganic–organic layered structure on Au(111). Surface Science. 2016 Oct 1;652:46-50. Available from, DOI: 10.1016/j.susc.2016.03.007
Rzeźnicka, I. I. ; Horino, H. ; Yagyu, K. ; Suzuki, T. ; Kajimoto, S. ; Fukumura, H./ Chlorine adlayer-templated growth of a hybrid inorganic–organic layered structure on Au(111). In: Surface Science. 2016 ; Vol. 652. pp. 46-50
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AU - Kajimoto,S.

AU - Fukumura,H.

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