Chlorine adlayer-templated growth of a hybrid inorganic–organic layered structure on Au(111)

I. I. Rzeźnicka, H. Horino, K. Yagyu, T. Suzuki, S. Kajimoto, H. Fukumura

Research output: Research - peer-reviewArticle

Abstract

Growth of a hybrid inorganic–organic layered structure on the Au(111) surface using a one-step solution growth is reported. The hybrid structure is consist of 4,4′-bipyridine [4,4′-BiPyH2]2 + cations, Cl anions and Au adatoms, provided from substrate by means of the adsorbate-induced surface phase transition of a surface reconstruction. Its surface and bulk structures were characterized by scanning tunneling microscopy (STM), secondary ion mass spectrometry (SIMS), and Raman spectroscopy. STM results reveal growth of the first [4,4′-BiPyH2]2 + layer on top of the [Formula presented] chlorine overlayer formed on the Au(111) surface. These two layers are found to provide a platform for a following three-dimensional growth facilitated by hydrogen bonding, aurophilic and π–π stacking interactions.

LanguageEnglish
Pages46-50
Number of pages5
JournalSurface Science
Volume652
DOIs
StatePublished - 2016 Oct 1
Externally publishedYes

Fingerprint

Chlorine
chlorine
Scanning tunneling microscopy
scanning tunneling microscopy
Surface reconstruction
Adatoms
Adsorbates
Secondary ion mass spectrometry
Anions
Raman spectroscopy
Cations
Hydrogen bonds
Phase transitions
Substrates
4,4'-bipyridyl
Negative ions
Positive ions
hybrid structures
secondary ion mass spectrometry
adatoms

Keywords

  • Au(111)
  • Aurophilic interaction
  • Bipyridine
  • Chlorine overlayer
  • Scanning tunneling microscopy
  • Tip-enhanced Raman spectroscopy

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

Chlorine adlayer-templated growth of a hybrid inorganic–organic layered structure on Au(111). / Rzeźnicka, I. I.; Horino, H.; Yagyu, K.; Suzuki, T.; Kajimoto, S.; Fukumura, H.

In: Surface Science, Vol. 652, 01.10.2016, p. 46-50.

Research output: Research - peer-reviewArticle

Rzeźnicka II, Horino H, Yagyu K, Suzuki T, Kajimoto S, Fukumura H. Chlorine adlayer-templated growth of a hybrid inorganic–organic layered structure on Au(111). Surface Science. 2016 Oct 1;652:46-50. Available from, DOI: 10.1016/j.susc.2016.03.007
Rzeźnicka, I. I. ; Horino, H. ; Yagyu, K. ; Suzuki, T. ; Kajimoto, S. ; Fukumura, H./ Chlorine adlayer-templated growth of a hybrid inorganic–organic layered structure on Au(111). In: Surface Science. 2016 ; Vol. 652. pp. 46-50
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AU - Fukumura,H.

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