Coatings and microstructures of monolithic TiB2 films and double layer and composite TiCN/TiB2 films from alkoxide solutions by thermal plasma CVD

S. Shimada, M. Takahashi, H. Kiyono, J. Tsujino

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16 Citations (Scopus)


Monolithic TiB2 films and double layer and composite TiCN-TiB2 films were deposited on Si wafers from a mixture of titanium tetra-ethoxide and boron tri-ethoxide solutions at a 1:2 mole ratio at 800 °C for 20 min by chemical vapor deposition in a thermal N2/H2 plasma. The TiB2 films were deposited without N2, while the double layer and composite TiCN-TiB2 films of various compositions were deposited by varying N2 flow rates in N2/H2 plasma. The surfaces and cross-sections of the films were observed by SEM, exhibiting the microstructures and thickness of the films. The relative atomic percentages of Ti, N, B, bonded and free C, and O in the films were determined semi-quantitatively from their XPS peak areas. Microstructures of the composite films with the composition 3TiC0.5N0.5/2TiB2 formed at N2 = 50 mL min- 1 were observed by TEM, revealing the sizes and orientations of the particles with the distribution of Ti and B elements in the film.

Original languageEnglish
Pages (from-to)6616-6621
Number of pages6
JournalThin Solid Films
Issue number19
Publication statusPublished - 2008 Aug 1
Externally publishedYes



  • Coating
  • Composite layer
  • Double layer
  • TiB
  • TiCN

ASJC Scopus subject areas

  • Surfaces, Coatings and Films
  • Condensed Matter Physics
  • Surfaces and Interfaces

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