Cost-effective nanoporous SiO₂-TiO₂ coatings on glass substrates with antireflective and self-cleaning properties

Simultaneous antireflective and self-cleaning properties have been realized by depositing double-layered SiO₂-TiO₂ coatings onto glass substrates using a combined sol-gel dip-coating process in which the two oxide layers were deposited in succession. The first layer is composed of a hybrid methyl-functionalized nanoporous SiO₂ material that provides on average a 6% anti-reflection gain. The degree of antireflectivity can be controlled by adjusting the thickness and refractive index by selecting suitable solvents and pore-forming agents in the coating mixture. The second layer is an ultrathin TiO₂ nanoporous layer deposited on top of antireflective layer. The high hardness of the TiO₂ top layer acts as a protection barrier toward mechanical damage and ensures the surface is self-cleaning. An average anti-reflectivity of 3.4% achieved over a spectrum range of 400-800nm for the optimal SiO₂-TiO₂ bilayers is obtained. It is found that a homogeneous pore size distribution in the SiO₂ layer introduced by using isopropanol as the solvent can compensate for the TiO₂ band edge absorption based on the optical interference that occurs between the two layers. These systems are easy to produce on a large scale at low cost and exhibit high mechanical and chemical durability. These materials are thus suitable for use as bifunctional antireflective and self-cleaning coatings for use as large substrates for solar cells.