Detection of deposition rate of plasma-polymerized films with a quartz crystal microbalance

Shigeru Kurosawa, Kazuya Kashima, Tomoya Hirokawa, Hidenobu Aizawa, Dae Sang Han, Björn Atthoff, Yasuo Yoshimi, Minoru Yoshimoto, Toshihiro Hirotsu, Jöns Hilborn

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The deposition rates of plasma-polymerized (pp-) films of vinyl acetate, vinyl trifluoroacetate, vinyl 2-chloroacetate, vinyl butanoate, vinyl pivalate, vinyl 2-butenoate, vinyl hexanoate and styrene are determined by the quartz crystal microbalance. Using the same polymerization conditions (100 W RF and 100 Pa vapor pressure) for the various monomers, the deposition rates were determined to be constant within the interval measured. The deposition rates of pp-vinyl acetate, pp-vinyl trifluoroacetate, pp-vinyl 2-chloroacetate, pp-vinyl butanoate, pp-vinyl pivalate, pp-vinyl 2-butenoate, vinyl hexanoate and pp-styrene were scattered on the different position of measure on the position of the lower electrode in the plasma polymerization equipment. The average deposition rate of pp-vinyl acetate was 0.28 μg/min. The average deposition rate of pp-vinyl trifluoroacetate was higher by 15 times, and that of pp- vinyl 2-chloroacetate was higher by 23 times than that of pp-vinyl acetate. The average deposition rate depended on the chemical structure of the monomer.

Original languageEnglish
Pages (from-to)33-38
Number of pages6
JournalJournal of Photopolymer Science and Technology
Volume13
Issue number1
Publication statusPublished - 2000
Externally publishedYes

Fingerprint

Quartz crystal microbalances
Deposition rates
Plasmas
Styrene
Monomers
Plasma polymerization
Vapor pressure
Polymerization
Electrodes
vinyl acetate
chloroacetic acid
vinyl trifluoroacetate

Keywords

  • Deposition rate
  • Plasma polymerization
  • Quartz crystal microbalance
  • Vinyl esters

ASJC Scopus subject areas

  • Materials Chemistry
  • Polymers and Plastics

Cite this

Kurosawa, S., Kashima, K., Hirokawa, T., Aizawa, H., Han, D. S., Atthoff, B., ... Hilborn, J. (2000). Detection of deposition rate of plasma-polymerized films with a quartz crystal microbalance. Journal of Photopolymer Science and Technology, 13(1), 33-38.

Detection of deposition rate of plasma-polymerized films with a quartz crystal microbalance. / Kurosawa, Shigeru; Kashima, Kazuya; Hirokawa, Tomoya; Aizawa, Hidenobu; Han, Dae Sang; Atthoff, Björn; Yoshimi, Yasuo; Yoshimoto, Minoru; Hirotsu, Toshihiro; Hilborn, Jöns.

In: Journal of Photopolymer Science and Technology, Vol. 13, No. 1, 2000, p. 33-38.

Research output: Contribution to journalArticle

Kurosawa, S, Kashima, K, Hirokawa, T, Aizawa, H, Han, DS, Atthoff, B, Yoshimi, Y, Yoshimoto, M, Hirotsu, T & Hilborn, J 2000, 'Detection of deposition rate of plasma-polymerized films with a quartz crystal microbalance', Journal of Photopolymer Science and Technology, vol. 13, no. 1, pp. 33-38.
Kurosawa, Shigeru ; Kashima, Kazuya ; Hirokawa, Tomoya ; Aizawa, Hidenobu ; Han, Dae Sang ; Atthoff, Björn ; Yoshimi, Yasuo ; Yoshimoto, Minoru ; Hirotsu, Toshihiro ; Hilborn, Jöns. / Detection of deposition rate of plasma-polymerized films with a quartz crystal microbalance. In: Journal of Photopolymer Science and Technology. 2000 ; Vol. 13, No. 1. pp. 33-38.
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