Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte

Atsushi Nakajima; Toshiki Tajima; Toshio Fuchigami

doi:10.5796/electrochemistry.74.618

Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte

Atsushi Nakajima, Toshiki Tajima, Toshio Fuchigami

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

We have successfully developed a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. In this system, solid-supported acids such as Amberlyst 15Dry (-SO₃H) serve as not only a promoter of the dissociation of KBr but also a supporting electrolyte. Anodic oxidation of some benzyl alcohols using KBr and Amberlyst 15Dry (-SO ₃H) in the presence of 2,6-lutidine was successfully carried out to provide the corresponding benzaldehydes in good to excellent yields.

Original language	English
Pages (from-to)	618-620
Number of pages	3
Journal	Electrochemistry
Volume	74
Issue number	8
DOIs	https://doi.org/10.5796/electrochemistry.74.618
Publication status	Published - 2006 Aug
Externally published	Yes

Keywords

Mediator
Potassium Bromide
Solid-Supported Acid
Supporting Electrolyte

ASJC Scopus subject areas

Electrochemistry

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10.5796/electrochemistry.74.618

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title = "Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte",

abstract = "We have successfully developed a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. In this system, solid-supported acids such as Amberlyst 15Dry (-SO3H) serve as not only a promoter of the dissociation of KBr but also a supporting electrolyte. Anodic oxidation of some benzyl alcohols using KBr and Amberlyst 15Dry (-SO 3H) in the presence of 2,6-lutidine was successfully carried out to provide the corresponding benzaldehydes in good to excellent yields.",

keywords = "Mediator, Potassium Bromide, Solid-Supported Acid, Supporting Electrolyte",

author = "Atsushi Nakajima and Toshiki Tajima and Toshio Fuchigami",

year = "2006",

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T1 - Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte

AU - Nakajima, Atsushi

AU - Tajima, Toshiki

AU - Fuchigami, Toshio

PY - 2006/8

Y1 - 2006/8

N2 - We have successfully developed a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. In this system, solid-supported acids such as Amberlyst 15Dry (-SO3H) serve as not only a promoter of the dissociation of KBr but also a supporting electrolyte. Anodic oxidation of some benzyl alcohols using KBr and Amberlyst 15Dry (-SO 3H) in the presence of 2,6-lutidine was successfully carried out to provide the corresponding benzaldehydes in good to excellent yields.

AB - We have successfully developed a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. In this system, solid-supported acids such as Amberlyst 15Dry (-SO3H) serve as not only a promoter of the dissociation of KBr but also a supporting electrolyte. Anodic oxidation of some benzyl alcohols using KBr and Amberlyst 15Dry (-SO 3H) in the presence of 2,6-lutidine was successfully carried out to provide the corresponding benzaldehydes in good to excellent yields.

KW - Mediator

KW - Potassium Bromide

KW - Solid-Supported Acid

KW - Supporting Electrolyte

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