Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte

Atsushi Nakajima; Toshiki Tajima; Toshio Fuchigami

doi:10.5796/electrochemistry.74.618

Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte

Atsushi Nakajima, Toshiki Tajima, Toshio Fuchigami

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

We have successfully developed a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. In this system, solid-supported acids such as Amberlyst 15Dry (-SO₃H) serve as not only a promoter of the dissociation of KBr but also a supporting electrolyte. Anodic oxidation of some benzyl alcohols using KBr and Amberlyst 15Dry (-SO ₃H) in the presence of 2,6-lutidine was successfully carried out to provide the corresponding benzaldehydes in good to excellent yields.

Original language	English
Pages (from-to)	618-620
Number of pages	3
Journal	Electrochemistry
Volume	74
Issue number	8
DOIs	https://doi.org/10.5796/electrochemistry.74.618
Publication status	Published - 2006 Aug
Externally published	Yes

Keywords

Mediator
Potassium Bromide
Solid-Supported Acid
Supporting Electrolyte

ASJC Scopus subject areas

Electrochemistry

Access to Document

10.5796/electrochemistry.74.618

Fingerprint Dive into the research topics of 'Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte'. Together they form a unique fingerprint.

Cite this

@article{06608977aaec4eb99a727f80070791f4,

title = "Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte",

abstract = "We have successfully developed a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. In this system, solid-supported acids such as Amberlyst 15Dry (-SO3H) serve as not only a promoter of the dissociation of KBr but also a supporting electrolyte. Anodic oxidation of some benzyl alcohols using KBr and Amberlyst 15Dry (-SO 3H) in the presence of 2,6-lutidine was successfully carried out to provide the corresponding benzaldehydes in good to excellent yields.",

keywords = "Mediator, Potassium Bromide, Solid-Supported Acid, Supporting Electrolyte",

author = "Atsushi Nakajima and Toshiki Tajima and Toshio Fuchigami",

year = "2006",

month = aug,

doi = "10.5796/electrochemistry.74.618",

language = "English",

volume = "74",

pages = "618--620",

journal = "Electrochemistry",

issn = "1344-3542",

publisher = "Electrochemical Society of Japan",

number = "8",

}

TY - JOUR

T1 - Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte

AU - Nakajima, Atsushi

AU - Tajima, Toshiki

AU - Fuchigami, Toshio

PY - 2006/8

Y1 - 2006/8

N2 - We have successfully developed a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. In this system, solid-supported acids such as Amberlyst 15Dry (-SO3H) serve as not only a promoter of the dissociation of KBr but also a supporting electrolyte. Anodic oxidation of some benzyl alcohols using KBr and Amberlyst 15Dry (-SO 3H) in the presence of 2,6-lutidine was successfully carried out to provide the corresponding benzaldehydes in good to excellent yields.

AB - We have successfully developed a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. In this system, solid-supported acids such as Amberlyst 15Dry (-SO3H) serve as not only a promoter of the dissociation of KBr but also a supporting electrolyte. Anodic oxidation of some benzyl alcohols using KBr and Amberlyst 15Dry (-SO 3H) in the presence of 2,6-lutidine was successfully carried out to provide the corresponding benzaldehydes in good to excellent yields.

KW - Mediator

KW - Potassium Bromide

KW - Solid-Supported Acid

KW - Supporting Electrolyte

UR - http://www.scopus.com/inward/record.url?scp=33749038626&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33749038626&partnerID=8YFLogxK

U2 - 10.5796/electrochemistry.74.618

DO - 10.5796/electrochemistry.74.618

M3 - Article

AN - SCOPUS:33749038626

VL - 74

SP - 618

EP - 620

JO - Electrochemistry

JF - Electrochemistry

SN - 1344-3542

IS - 8

ER -

Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this