Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte

Atsushi Nakajima, Toshiki Tajima, Toshio Fuchigami

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

We have successfully developed a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. In this system, solid-supported acids such as Amberlyst 15Dry (-SO3H) serve as not only a promoter of the dissociation of KBr but also a supporting electrolyte. Anodic oxidation of some benzyl alcohols using KBr and Amberlyst 15Dry (-SO 3H) in the presence of 2,6-lutidine was successfully carried out to provide the corresponding benzaldehydes in good to excellent yields.

Original languageEnglish
Pages (from-to)618-620
Number of pages3
JournalElectrochemistry
Volume74
Issue number8
Publication statusPublished - 2006 Aug
Externally publishedYes

Fingerprint

Electrolytes
Acids
Benzyl Alcohols
Anodic oxidation
Benzaldehydes
Alcohols
potassium bromide
2,6-lutidine

Keywords

  • Mediator
  • Potassium Bromide
  • Solid-Supported Acid
  • Supporting Electrolyte

ASJC Scopus subject areas

  • Electrochemistry

Cite this

Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. / Nakajima, Atsushi; Tajima, Toshiki; Fuchigami, Toshio.

In: Electrochemistry, Vol. 74, No. 8, 08.2006, p. 618-620.

Research output: Contribution to journalArticle

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