Abstract
We have successfully developed a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. In this system, solid-supported acids such as Amberlyst 15Dry (-SO3H) serve as not only a promoter of the dissociation of KBr but also a supporting electrolyte. Anodic oxidation of some benzyl alcohols using KBr and Amberlyst 15Dry (-SO 3H) in the presence of 2,6-lutidine was successfully carried out to provide the corresponding benzaldehydes in good to excellent yields.
| Original language | English |
|---|---|
| Pages (from-to) | 618-620 |
| Number of pages | 3 |
| Journal | Electrochemistry |
| Volume | 74 |
| Issue number | 8 |
| Publication status | Published - 2006 Aug |
| Externally published | Yes |
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Keywords
- Mediator
- Potassium Bromide
- Solid-Supported Acid
- Supporting Electrolyte
ASJC Scopus subject areas
- Electrochemistry
Cite this
Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. / Nakajima, Atsushi; Tajima, Toshiki; Fuchigami, Toshio.
In: Electrochemistry, Vol. 74, No. 8, 08.2006, p. 618-620.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte
AU - Nakajima, Atsushi
AU - Tajima, Toshiki
AU - Fuchigami, Toshio
PY - 2006/8
Y1 - 2006/8
N2 - We have successfully developed a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. In this system, solid-supported acids such as Amberlyst 15Dry (-SO3H) serve as not only a promoter of the dissociation of KBr but also a supporting electrolyte. Anodic oxidation of some benzyl alcohols using KBr and Amberlyst 15Dry (-SO 3H) in the presence of 2,6-lutidine was successfully carried out to provide the corresponding benzaldehydes in good to excellent yields.
AB - We have successfully developed a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. In this system, solid-supported acids such as Amberlyst 15Dry (-SO3H) serve as not only a promoter of the dissociation of KBr but also a supporting electrolyte. Anodic oxidation of some benzyl alcohols using KBr and Amberlyst 15Dry (-SO 3H) in the presence of 2,6-lutidine was successfully carried out to provide the corresponding benzaldehydes in good to excellent yields.
KW - Mediator
KW - Potassium Bromide
KW - Solid-Supported Acid
KW - Supporting Electrolyte
UR - http://www.scopus.com/inward/record.url?scp=33749038626&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33749038626&partnerID=8YFLogxK
M3 - Article
VL - 74
SP - 618
EP - 620
JO - Electrochemistry
JF - Electrochemistry
SN - 1344-3542
IS - 8
ER -