Abstract
We have successfully developed a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. In this system, solid-supported acids such as Amberlyst 15Dry (-SO3H) serve as not only a promoter of the dissociation of KBr but also a supporting electrolyte. Anodic oxidation of some benzyl alcohols using KBr and Amberlyst 15Dry (-SO 3H) in the presence of 2,6-lutidine was successfully carried out to provide the corresponding benzaldehydes in good to excellent yields.
| Original language | English |
|---|---|
| Pages (from-to) | 618-620 |
| Number of pages | 3 |
| Journal | Electrochemistry |
| Volume | 74 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 2006 Aug |
Keywords
- Mediator
- Potassium Bromide
- Solid-Supported Acid
- Supporting Electrolyte
ASJC Scopus subject areas
- Electrochemistry
Fingerprint Dive into the research topics of 'Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte'. Together they form a unique fingerprint.
Cite this
Nakajima, A., Tajima, T., & Fuchigami, T. (2006). Development of a novel electrolytic system using KBr as a mediator and solid-supported acids as a supporting electrolyte. Electrochemistry, 74(8), 618-620. https://doi.org/10.5796/electrochemistry.74.618