Dynamic Ag+-intercalation with AgSnSe2 nano-precipitates in Cl-doped polycrystalline SnSe2 toward ultra-high thermoelectric performance

Chengyan Liu, Zhiwei Huang, Dianhui Wang, Xiuxia Wang, Lei Miao, Xiaoyang Wang, Shaohai Wu, Nozomu Toyama, Toru Asaka, Junliang Chen, Eiji Nishibori, Li Dong Zhao

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7 Citations (Scopus)


Recently, thermoelectric lead-free selenides have attracted great attention due to their earth-abundant, low-cost and environment-friendly characteristics. Here we report a new strategy to simultaneously enhance the electronic transport properties and reduce the thermal conductivity of polycrystalline SnSe2. By combining weak van der Waals bonding with the mobile behavior of Ag+ ions, the carrier concentration is optimized over a wide temperature range, which can be attributed to the dynamic Ag+-intercalation into the van der Waals gap from the Ag+ ion reservoir AgSnSe2. On account of additional electrical bridges between interlayers contributed by the intercalated Ag+ ions and weak anisotropy, an exciting high power factor of up to ∼7.46 μW cm−1 K−2 at 789 K is achieved along the pressing direction. In addition, the thermal conductivity is simultaneously reduced to ∼0.57 W m−1 K−1 at 789 K, owing to numerous line defects, phase interfaces, twin boundaries, dislocations and intercalated atomic layers generated after Ag introduction, as well as the anharmonic vibration of Ag+ ions. As a result, a record peak ZT of ∼1.03 at 789 K is realized along the pressing direction, which is ∼1.6 times larger than the highest reported value (0.63) of polycrystalline SnSe2 and even comparable to that of p-type polycrystalline SnSe. This study opens a new way to achieve ultra-high thermoelectric performance, especially in layered materials.

Original languageEnglish
Pages (from-to)9761-9772
Number of pages12
JournalJournal of Materials Chemistry A
Issue number16
Publication statusPublished - 2019
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

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    Liu, C., Huang, Z., Wang, D., Wang, X., Miao, L., Wang, X., Wu, S., Toyama, N., Asaka, T., Chen, J., Nishibori, E., & Zhao, L. D. (2019). Dynamic Ag+-intercalation with AgSnSe2 nano-precipitates in Cl-doped polycrystalline SnSe2 toward ultra-high thermoelectric performance. Journal of Materials Chemistry A, 7(16), 9761-9772. https://doi.org/10.1039/c9ta01678c