Effect of Ambient gas and temperature on crystallization of boron nitride spheres prepared by vapor phase pyrolysis of Ammonia Borane

Yuting Wang, Yasunori Yamamoto, Hajime Kiyono, Shiro Shimada

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Synthesis of boron nitride spheres (BNS) was achieved by vapor phase pyrolysis of ammonia borane (BH3NH3) using two independently temperature-controlled furnaces in a glove box filled with N 2. The BNS were heated at 1300°-1700°C in flowing NH 3, N2, or Ar by multistep heat treatment. The sizes of the BNS could be controlled by heating BH3NH3 at different rates (1°C/min: 300-800 nm, 5°C/min: 300 nm-1.2 μm and 10°C/min: 300 nm-1.8 μm). The microstructures of BNS heated in different ambient gases were observed using transmission electron microscopy with selected area electron diffraction. NH3 gas produced BNS with well-crystallized surface shells and amorphous cores whereas N2 and Ar gases crystallized the entire BNS. It is evident that of these three ambient gases (NH3, N2, and Ar), N2 gas significantly enhances the crystallization of BN with randomly oriented grains.

Original languageEnglish
Pages (from-to)787-792
Number of pages6
JournalJournal of the American Ceramic Society
Volume92
Issue number4
DOIs
Publication statusPublished - 2009 Apr
Externally publishedYes

Fingerprint

Boranes
Boron nitride
Crystallization
Ammonia
Pyrolysis
Gases
Vapors
Temperature
Electron diffraction
boron nitride
Furnaces
Heat treatment
Transmission electron microscopy
Heating
Microstructure

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

Cite this

Effect of Ambient gas and temperature on crystallization of boron nitride spheres prepared by vapor phase pyrolysis of Ammonia Borane. / Wang, Yuting; Yamamoto, Yasunori; Kiyono, Hajime; Shimada, Shiro.

In: Journal of the American Ceramic Society, Vol. 92, No. 4, 04.2009, p. 787-792.

Research output: Contribution to journalArticle

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