Abstract
We investigated various areas of impurity-free YBa2Cu3O7-δ single crystals with Raman spectroscopy. A definite correlation between the appearance of the group- theoretically forbidden chain-related Raman lines at 232 and 598 cm-1 and the superconductivity-induced self-energy effects observed for the 340 cm-1 B1g-like mode was established: Disorder in the chains in pure crystals has a similar effect as the introduction of impurity atoms, both leading to an increased gap value for 2Δ/kTc as deduced from the phonon self-energy effects. The absence of the forbidden chain modes in the Raman spectra may be used as an extremely sensitive quality criterion of impurity-free crystals.
Original language | English |
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Pages (from-to) | 643-647 |
Number of pages | 5 |
Journal | Solid State Communications |
Volume | 80 |
Issue number | 8 |
DOIs | |
Publication status | Published - 1991 Nov |
Externally published | Yes |
ASJC Scopus subject areas
- Chemistry(all)
- Condensed Matter Physics
- Materials Chemistry