Abstract
The effect of different plasticizers in the sensing membrane on the performance of a surfactant ISE based on a PVC membrane with no added ion-exchanger was investigated, o-nitrophenyl octyl ether (NPOE), o-nitrophenyl decyl ether (NPDE), o-nitrophenyl dodecyl ether (NPDOE) and o-nitrophenyl tetradecyl ether (NPTE) were used as plasticizers. Electrodes based on NPDE, NPDOE and NPTE produced better results than NPOE-plasticized PVC membrane electrodes in terms of low detection limits. Electrodes based on NPDE, NPDOE and NPTE displayed a Nernstian slope in the concentration range of 10-6 to 10-2 M. NPOE-plasticized PVC membrane electrodes displayed a Nernstian slope in the concentration range of 10-5 to 10-2 M. The three electrodes other than the NPOE-plasticized PVC membrane electrode showed a similar performance to that of the NPOE-plasticized PVC membrane electrode concerning low detection limits and slope sensitivity. The four electrodes examined in this study are excellently selective for the dodecyltrimethyl-ammonium ion over inorganic anions, but interference from other cationic surfactants such as tetradecyltrimethylammonium ions is significant. With respect to slope sensitivity, selectivity, response time and pH effect, the four electrodes showed a similar performance.
| Original language | English |
|---|---|
| Pages (from-to) | 217-220 |
| Number of pages | 4 |
| Journal | Microchimica Acta |
| Volume | 144 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - 2004 |
| Externally published | Yes |
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Keywords
- Cationic surfactant-selective electrode
- No added ion-exchanger
- o-nitrophenyl octyl ether derivatives
- Plasticizer
- PVC membrane electrode
ASJC Scopus subject areas
- Analytical Chemistry
Cite this
Effect of plasticizer on the performance of the surfactant-selective electrode based on a poly(vinyl chloride) membrane with no added ion-exchanger. / Masadome, Takashi; Yang, Ji Guang; Imato, Toshihiko.
In: Microchimica Acta, Vol. 144, No. 4, 2004, p. 217-220.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Effect of plasticizer on the performance of the surfactant-selective electrode based on a poly(vinyl chloride) membrane with no added ion-exchanger
AU - Masadome, Takashi
AU - Yang, Ji Guang
AU - Imato, Toshihiko
PY - 2004
Y1 - 2004
N2 - The effect of different plasticizers in the sensing membrane on the performance of a surfactant ISE based on a PVC membrane with no added ion-exchanger was investigated, o-nitrophenyl octyl ether (NPOE), o-nitrophenyl decyl ether (NPDE), o-nitrophenyl dodecyl ether (NPDOE) and o-nitrophenyl tetradecyl ether (NPTE) were used as plasticizers. Electrodes based on NPDE, NPDOE and NPTE produced better results than NPOE-plasticized PVC membrane electrodes in terms of low detection limits. Electrodes based on NPDE, NPDOE and NPTE displayed a Nernstian slope in the concentration range of 10-6 to 10-2 M. NPOE-plasticized PVC membrane electrodes displayed a Nernstian slope in the concentration range of 10-5 to 10-2 M. The three electrodes other than the NPOE-plasticized PVC membrane electrode showed a similar performance to that of the NPOE-plasticized PVC membrane electrode concerning low detection limits and slope sensitivity. The four electrodes examined in this study are excellently selective for the dodecyltrimethyl-ammonium ion over inorganic anions, but interference from other cationic surfactants such as tetradecyltrimethylammonium ions is significant. With respect to slope sensitivity, selectivity, response time and pH effect, the four electrodes showed a similar performance.
AB - The effect of different plasticizers in the sensing membrane on the performance of a surfactant ISE based on a PVC membrane with no added ion-exchanger was investigated, o-nitrophenyl octyl ether (NPOE), o-nitrophenyl decyl ether (NPDE), o-nitrophenyl dodecyl ether (NPDOE) and o-nitrophenyl tetradecyl ether (NPTE) were used as plasticizers. Electrodes based on NPDE, NPDOE and NPTE produced better results than NPOE-plasticized PVC membrane electrodes in terms of low detection limits. Electrodes based on NPDE, NPDOE and NPTE displayed a Nernstian slope in the concentration range of 10-6 to 10-2 M. NPOE-plasticized PVC membrane electrodes displayed a Nernstian slope in the concentration range of 10-5 to 10-2 M. The three electrodes other than the NPOE-plasticized PVC membrane electrode showed a similar performance to that of the NPOE-plasticized PVC membrane electrode concerning low detection limits and slope sensitivity. The four electrodes examined in this study are excellently selective for the dodecyltrimethyl-ammonium ion over inorganic anions, but interference from other cationic surfactants such as tetradecyltrimethylammonium ions is significant. With respect to slope sensitivity, selectivity, response time and pH effect, the four electrodes showed a similar performance.
KW - Cationic surfactant-selective electrode
KW - No added ion-exchanger
KW - o-nitrophenyl octyl ether derivatives
KW - Plasticizer
KW - PVC membrane electrode
UR - http://www.scopus.com/inward/record.url?scp=2142648778&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=2142648778&partnerID=8YFLogxK
U2 - 10.1007/s00604-003-0112-3
DO - 10.1007/s00604-003-0112-3
M3 - Article
VL - 144
SP - 217
EP - 220
JO - Microchimica Acta
JF - Microchimica Acta
SN - 0026-3672
IS - 4
ER -