Electrocatalytic debromination of organic bromides using a cobalt(II)salen complex in ionic liquids

Yi Shen, Toshiki Tajima, Mahito Atobe, Toshio Fuchigami

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The catalytic effect of a Co(II)salen mediator on the reduction of cyclic vic-dibromide was investigated in ionic liquids by cyclic voltammetry. Macro-scale controlled potential electrolysis gave the corresponding debrominated product in moderate to good yields. The workup after electrolysis in an ionic liquid proved to be much simpler than that in organic solvents. The possibility of reuse of the ionic liquid was demonstrated to some extent.

Original languageEnglish
Pages (from-to)849-851
Number of pages3
JournalElectrochemistry
Volume72
Issue number12
Publication statusPublished - 2004 Dec
Externally publishedYes

Fingerprint

Ionic Liquids
Cobalt
Bromides
Ionic liquids
Electrolysis
Organic solvents
Cyclic voltammetry
Macros
disalicylaldehyde ethylenediamine

Keywords

  • Controlled Potential Electrolysis
  • Ionic Liquid
  • Mediator

ASJC Scopus subject areas

  • Electrochemistry

Cite this

Electrocatalytic debromination of organic bromides using a cobalt(II)salen complex in ionic liquids. / Shen, Yi; Tajima, Toshiki; Atobe, Mahito; Fuchigami, Toshio.

In: Electrochemistry, Vol. 72, No. 12, 12.2004, p. 849-851.

Research output: Contribution to journalArticle

Shen, Yi ; Tajima, Toshiki ; Atobe, Mahito ; Fuchigami, Toshio. / Electrocatalytic debromination of organic bromides using a cobalt(II)salen complex in ionic liquids. In: Electrochemistry. 2004 ; Vol. 72, No. 12. pp. 849-851.
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