Electrocatalytic oxygen reduction on nitrogen-doped carbon nanoparticles derived from cyano-aromatic molecules via a solution plasma approach

Gasidit Panomsuwan, Nagahiro Saito, Takahiro Ishizaki

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

Metal-free nitrogen-doped carbon nanoparticles (NCNPs) have been synthesized via a solution plasma process with the potential to achieve uniformly distributed nitrogen atoms. A set of cyano-aromatic molecules, including benzonitrile, 2-cyanopyridine, and cyanopyrazine, were used as a single-source precursor in the synthesis without the addition of a metal catalyst source. The resultant NCNPs reveal uniformly nanosized particles (20-40 nm) and an interconnected hierarchical pore structure with a high specific surface area (210-250 m2 g-1). The difference in carbon/nitrogen mole ratios of organic precursors gives rise to the variation of nitrogen-doping level in NCNPs from 0.63 to 1.94 atom %. Detailed electrochemical evaluation toward the oxygen reduction reaction (ORR) demonstrates that NCNPs exhibit a significant improvement in terms of both onset potential and current density under alkaline and acidic conditions. The predominant distribution of graphitic-N and pyridinic-N sites on NCNPs plays an essential role in enhancing the ORR activity and the selectivity toward a four-electron reduction pathway. More importantly, NCNPs possess excellent robust long-term durability and strong methanol tolerance compared with those of a commercial Pt/carbon catalyst.

Original languageEnglish
Pages (from-to)411-420
Number of pages10
JournalCarbon
Volume98
DOIs
Publication statusPublished - 2016 Mar 1

ASJC Scopus subject areas

  • Chemistry(all)

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