Electrochemical reduction of uranium(VI) in nitric acid-hydrazine solution on glassy carbon electrode

Y. Z. Wei, B. Fang, Tsuyoshi Arai, M. Kumagai

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Electrochemical reduction of U(VI) in nitric acid-hydrazine solution is greatly influenced by the concentration of nitric acid. In low acidity nitric acid solution such as 0.1M (M=mol/dm 3) HNO 3, U(VI) was firstly reduced to U(V) and then partially reduced to U(IV). In high acidity nitric acid solution, e.g., 3-6M HNO 3, an electrode process of two-electron transfer was involved in the reduction of U(VI). A higher U(IV) yield could be achieved in nitric acid solution with higher concentration. Hydrazine was very effective in suppressing the reduction of concentrated nitric acid, and the optimal concentration of hydrazine added was 0.075 to 0.15M in 6M HNO 3.

Original languageEnglish
Pages (from-to)409-415
Number of pages7
JournalJournal of Radioanalytical and Nuclear Chemistry
Volume262
Issue number2
DOIs
Publication statusPublished - 2004
Externally publishedYes

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hydrazine
Nitric Acid
Uranium
Hydrazine
Glassy carbon
Nitric acid
Electrodes
Acidity

ASJC Scopus subject areas

  • Analytical Chemistry
  • Inorganic Chemistry
  • Nuclear Energy and Engineering

Cite this

Electrochemical reduction of uranium(VI) in nitric acid-hydrazine solution on glassy carbon electrode. / Wei, Y. Z.; Fang, B.; Arai, Tsuyoshi; Kumagai, M.

In: Journal of Radioanalytical and Nuclear Chemistry, Vol. 262, No. 2, 2004, p. 409-415.

Research output: Contribution to journalArticle

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