TY - JOUR
T1 - Electrolytic partial fluorination of organic compounds. Part 78
T2 - Regioselective anodic fluorination of 2-oxazolidinones
AU - Cao, Yi
AU - Suzuki, Katsutoshi
AU - Tajima, Toshiki
AU - Fuchigami, Toshio
N1 - Funding Information:
This research was supported by a Grant-in-Aid for Scientific Research on Priority Areas (A) ‘Exploitation of Multi-Element Cyclic Molecules’ from the Ministry of Education, Culture, Sports, Science and Technology, Japan.
PY - 2005/7/11
Y1 - 2005/7/11
N2 - Various 2-oxazolidinones were galvanostatically electrooxidized in the presence of various fluoride salts. It was found that a fluorine atom was introduced to the α-position of the nitrogen atom of N-acyl- and N-alkoxycarbonyl-2-oxazolidinones to provide the corresponding α-fluorinated products in moderate to good yields. In the case of N-phenoxycarbonyl derivative, fluorination took place on the phenyl group selectively.
AB - Various 2-oxazolidinones were galvanostatically electrooxidized in the presence of various fluoride salts. It was found that a fluorine atom was introduced to the α-position of the nitrogen atom of N-acyl- and N-alkoxycarbonyl-2-oxazolidinones to provide the corresponding α-fluorinated products in moderate to good yields. In the case of N-phenoxycarbonyl derivative, fluorination took place on the phenyl group selectively.
KW - 2-Oxazolidinone
KW - Electrochemical fluorination
KW - Fluorinated 2-oxazolidinone
KW - Partial fluorination
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U2 - 10.1016/j.tet.2005.04.057
DO - 10.1016/j.tet.2005.04.057
M3 - Article
AN - SCOPUS:20444448033
VL - 61
SP - 6854
EP - 6859
JO - Tetrahedron
JF - Tetrahedron
SN - 0040-4020
IS - 28
ER -