Electroreductive hydrogenation of activated olefins using the concept of site isolation

Shinsuke Tomida; Ryohei Tsuda; Shiho Furukawa; Marie Saito; Toshiki Tajima

doi:10.1016/j.elecom.2016.10.015

Electroreductive hydrogenation of activated olefins using the concept of site isolation

Shinsuke Tomida, Ryohei Tsuda, Shiho Furukawa, Marie Saito, Toshiki Tajima

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Electroreductive hydrogenation of activated olefins was investigated using the concept of site isolation. It was shown by electrochemical measurements as well as preparative electrolyses that the use of silica gel-supported sulfonic acid (Si-SO₃H) promotes the protonation step in electroreductive hydrogenation of activated olefins without electroreductive destruction at the cathode. On the basis of the concept of site isolation, electroreductive hydrogenation of several activated olefins was successfully carried out to provide the corresponding hydrogenation products in high yields.

Original language	English
Pages (from-to)	46-49
Number of pages	4
Journal	Electrochemistry Communications
Volume	73
DOIs	https://doi.org/10.1016/j.elecom.2016.10.015
Publication status	Published - 2016 Dec 1

Keywords

Activated olefin
Cation exchange
Electroreductive hydrogenation
Site isolation
Solid-supported acid

ASJC Scopus subject areas

Electrochemistry

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10.1016/j.elecom.2016.10.015

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title = "Electroreductive hydrogenation of activated olefins using the concept of site isolation",

abstract = "Electroreductive hydrogenation of activated olefins was investigated using the concept of site isolation. It was shown by electrochemical measurements as well as preparative electrolyses that the use of silica gel-supported sulfonic acid (Si-SO3H) promotes the protonation step in electroreductive hydrogenation of activated olefins without electroreductive destruction at the cathode. On the basis of the concept of site isolation, electroreductive hydrogenation of several activated olefins was successfully carried out to provide the corresponding hydrogenation products in high yields.",

keywords = "Activated olefin, Cation exchange, Electroreductive hydrogenation, Site isolation, Solid-supported acid",

author = "Shinsuke Tomida and Ryohei Tsuda and Shiho Furukawa and Marie Saito and Toshiki Tajima",

note = "Funding Information: This work was supported by a Grant-in-Aid for Young Scientists (A) (No. 23685036 ) from The Ministry of Education, Culture, Sports, Science and Technology, Japan . Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

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T1 - Electroreductive hydrogenation of activated olefins using the concept of site isolation

AU - Tomida, Shinsuke

AU - Tsuda, Ryohei

AU - Furukawa, Shiho

AU - Saito, Marie

AU - Tajima, Toshiki

N1 - Funding Information: This work was supported by a Grant-in-Aid for Young Scientists (A) (No. 23685036 ) from The Ministry of Education, Culture, Sports, Science and Technology, Japan . Publisher Copyright: © 2016 Elsevier B.V.

PY - 2016/12/1

Y1 - 2016/12/1

N2 - Electroreductive hydrogenation of activated olefins was investigated using the concept of site isolation. It was shown by electrochemical measurements as well as preparative electrolyses that the use of silica gel-supported sulfonic acid (Si-SO3H) promotes the protonation step in electroreductive hydrogenation of activated olefins without electroreductive destruction at the cathode. On the basis of the concept of site isolation, electroreductive hydrogenation of several activated olefins was successfully carried out to provide the corresponding hydrogenation products in high yields.

AB - Electroreductive hydrogenation of activated olefins was investigated using the concept of site isolation. It was shown by electrochemical measurements as well as preparative electrolyses that the use of silica gel-supported sulfonic acid (Si-SO3H) promotes the protonation step in electroreductive hydrogenation of activated olefins without electroreductive destruction at the cathode. On the basis of the concept of site isolation, electroreductive hydrogenation of several activated olefins was successfully carried out to provide the corresponding hydrogenation products in high yields.

KW - Activated olefin

KW - Cation exchange

KW - Electroreductive hydrogenation

KW - Site isolation

KW - Solid-supported acid

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DO - 10.1016/j.elecom.2016.10.015

M3 - Article

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VL - 73

SP - 46

EP - 49

JO - Electrochemistry Communications

JF - Electrochemistry Communications

ER -

Electroreductive hydrogenation of activated olefins using the concept of site isolation

Abstract

Keywords

ASJC Scopus subject areas

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