Enhanced adsorption of small gas molecules in metal (Cu2+, Pd2+, Pt2+) complexes induced by ligand fluorination

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7 Citations (Scopus)

Abstract

Fully fluorinated coordination complexes, [M(L)2] (M = Cu2+, Pd2+, Pt2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO2 and metal ion-selective adsorption of small gas molecules such as N2, O2, H2, NO, and CH4, while the corresponding non-fluorinated complexes show no guest encapsulation.

Original languageEnglish
Pages (from-to)6263-6266
Number of pages4
JournalCrystEngComm
Volume19
Issue number42
DOIs
Publication statusPublished - 2017 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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