Enhanced adsorption of small gas molecules in metal (Cu2+, Pd2+, Pt2+) complexes induced by ligand fluorination

Akiko Hori; Ryu Gonda; Izabela Irena Rzeznicka

doi:10.1039/c7ce01413a

Enhanced adsorption of small gas molecules in metal (Cu²⁺, Pd²⁺, Pt²⁺) complexes induced by ligand fluorination

Akiko Hori, Ryu Gonda, Izabela Irena Rzeznicka

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Fully fluorinated coordination complexes, [M(L)₂] (M = Cu²⁺, Pd²⁺, Pt²⁺ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO₂ and metal ion-selective adsorption of small gas molecules such as N₂, O₂, H₂, NO, and CH₄, while the corresponding non-fluorinated complexes show no guest encapsulation.

Original language	English
Pages (from-to)	6263-6266
Number of pages	4
Journal	CrystEngComm
Volume	19
Issue number	42
DOIs	https://doi.org/10.1039/c7ce01413a
Publication status	Published - 2017 Jan 1

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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abstract = "Fully fluorinated coordination complexes, [M(L)2] (M = Cu2+, Pd2+, Pt2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO2 and metal ion-selective adsorption of small gas molecules such as N2, O2, H2, NO, and CH4, while the corresponding non-fluorinated complexes show no guest encapsulation.",

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AB - Fully fluorinated coordination complexes, [M(L)2] (M = Cu2+, Pd2+, Pt2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO2 and metal ion-selective adsorption of small gas molecules such as N2, O2, H2, NO, and CH4, while the corresponding non-fluorinated complexes show no guest encapsulation.

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