Abstract
Fully fluorinated coordination complexes, [M(L)2] (M = Cu2+, Pd2+, Pt2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO2 and metal ion-selective adsorption of small gas molecules such as N2, O2, H2, NO, and CH4, while the corresponding non-fluorinated complexes show no guest encapsulation.
| Original language | English |
|---|---|
| Pages (from-to) | 6263-6266 |
| Number of pages | 4 |
| Journal | CrystEngComm |
| Volume | 19 |
| Issue number | 42 |
| DOIs | |
| Publication status | Published - 2017 Jan 1 |
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ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Enhanced adsorption of small gas molecules in metal (Cu2+, Pd2+, Pt2+) complexes induced by ligand fluorination. / Hori, Akiko; Gonda, Ryu; Rzeznicka, Izabela Irena.
In: CrystEngComm, Vol. 19, No. 42, 01.01.2017, p. 6263-6266.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Enhanced adsorption of small gas molecules in metal (Cu2+, Pd2+, Pt2+) complexes induced by ligand fluorination
AU - Hori, Akiko
AU - Gonda, Ryu
AU - Rzeznicka, Izabela Irena
PY - 2017/1/1
Y1 - 2017/1/1
N2 - Fully fluorinated coordination complexes, [M(L)2] (M = Cu2+, Pd2+, Pt2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO2 and metal ion-selective adsorption of small gas molecules such as N2, O2, H2, NO, and CH4, while the corresponding non-fluorinated complexes show no guest encapsulation.
AB - Fully fluorinated coordination complexes, [M(L)2] (M = Cu2+, Pd2+, Pt2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO2 and metal ion-selective adsorption of small gas molecules such as N2, O2, H2, NO, and CH4, while the corresponding non-fluorinated complexes show no guest encapsulation.
UR - http://www.scopus.com/inward/record.url?scp=85032619400&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85032619400&partnerID=8YFLogxK
U2 - 10.1039/c7ce01413a
DO - 10.1039/c7ce01413a
M3 - Article
VL - 19
SP - 6263
EP - 6266
JO - CrystEngComm
JF - CrystEngComm
SN - 1466-8033
IS - 42
ER -