Enhanced adsorption of small gas molecules in metal (Cu2+, Pd2+, Pt2+) complexes induced by ligand fluorination

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Fully fluorinated coordination complexes, [M(L)2] (M = Cu2+, Pd2+, Pt2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO2 and metal ion-selective adsorption of small gas molecules such as N2, O2, H2, NO, and CH4, while the corresponding non-fluorinated complexes show no guest encapsulation.

Original languageEnglish
Pages (from-to)6263-6266
Number of pages4
JournalCrystEngComm
Volume19
Issue number42
DOIs
Publication statusPublished - 2017 Jan 1

Fingerprint

Fluorination
fluorination
Coordination Complexes
Encapsulation
Metal ions
Gases
Metals
Ligands
Adsorption
ligands
Molecules
adsorption
gases
metals
molecules
metal ions
ions

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Enhanced adsorption of small gas molecules in metal (Cu2+, Pd2+, Pt2+) complexes induced by ligand fluorination. / Hori, Akiko; Gonda, Ryu; Rzeznicka, Izabela Irena.

In: CrystEngComm, Vol. 19, No. 42, 01.01.2017, p. 6263-6266.

Research output: Contribution to journalArticle

@article{ce652ffc3b744dbc8a0cdc24ac543503,
title = "Enhanced adsorption of small gas molecules in metal (Cu2+, Pd2+, Pt2+) complexes induced by ligand fluorination",
abstract = "Fully fluorinated coordination complexes, [M(L)2] (M = Cu2+, Pd2+, Pt2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO2 and metal ion-selective adsorption of small gas molecules such as N2, O2, H2, NO, and CH4, while the corresponding non-fluorinated complexes show no guest encapsulation.",
author = "Akiko Hori and Ryu Gonda and Rzeznicka, {Izabela Irena}",
year = "2017",
month = "1",
day = "1",
doi = "10.1039/c7ce01413a",
language = "English",
volume = "19",
pages = "6263--6266",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "42",

}

TY - JOUR

T1 - Enhanced adsorption of small gas molecules in metal (Cu2+, Pd2+, Pt2+) complexes induced by ligand fluorination

AU - Hori, Akiko

AU - Gonda, Ryu

AU - Rzeznicka, Izabela Irena

PY - 2017/1/1

Y1 - 2017/1/1

N2 - Fully fluorinated coordination complexes, [M(L)2] (M = Cu2+, Pd2+, Pt2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO2 and metal ion-selective adsorption of small gas molecules such as N2, O2, H2, NO, and CH4, while the corresponding non-fluorinated complexes show no guest encapsulation.

AB - Fully fluorinated coordination complexes, [M(L)2] (M = Cu2+, Pd2+, Pt2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO2 and metal ion-selective adsorption of small gas molecules such as N2, O2, H2, NO, and CH4, while the corresponding non-fluorinated complexes show no guest encapsulation.

UR - http://www.scopus.com/inward/record.url?scp=85032619400&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85032619400&partnerID=8YFLogxK

U2 - 10.1039/c7ce01413a

DO - 10.1039/c7ce01413a

M3 - Article

AN - SCOPUS:85032619400

VL - 19

SP - 6263

EP - 6266

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 42

ER -