TY - JOUR
T1 - Enhanced adsorption of small gas molecules in metal (Cu2+, Pd2+, Pt2+) complexes induced by ligand fluorination
AU - Hori, Akiko
AU - Gonda, Ryu
AU - Rzeznicka, Izabela I.
N1 - Funding Information:
This work was supported by Shiseido Female Researcher Science Grant 2015. A. H. thanks Mr. Kyosuke Nakajima of Kitasato University and Prof. Satoshi Takamizawa of Yokohama City University for experimental support. We also thank Mr. Motoharu Nakano of the MicrotracBel, Japan for testing our samples.
Publisher Copyright:
© 2017 The Royal Society of Chemistry.
PY - 2017
Y1 - 2017
N2 - Fully fluorinated coordination complexes, [M(L)2] (M = Cu2+, Pd2+, Pt2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO2 and metal ion-selective adsorption of small gas molecules such as N2, O2, H2, NO, and CH4, while the corresponding non-fluorinated complexes show no guest encapsulation.
AB - Fully fluorinated coordination complexes, [M(L)2] (M = Cu2+, Pd2+, Pt2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO2 and metal ion-selective adsorption of small gas molecules such as N2, O2, H2, NO, and CH4, while the corresponding non-fluorinated complexes show no guest encapsulation.
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U2 - 10.1039/c7ce01413a
DO - 10.1039/c7ce01413a
M3 - Article
AN - SCOPUS:85032619400
VL - 19
SP - 6263
EP - 6266
JO - CrystEngComm
JF - CrystEngComm
SN - 1466-8033
IS - 42
ER -