TY - JOUR
T1 - Enhanced adsorption of small gas molecules in metal (Cu2+, Pd2+, Pt2+) complexes induced by ligand fluorination
AU - Hori, Akiko
AU - Gonda, Ryu
AU - Rzeznicka, Izabela Irena
PY - 2017/1/1
Y1 - 2017/1/1
N2 - Fully fluorinated coordination complexes, [M(L)2] (M = Cu2+, Pd2+, Pt2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO2 and metal ion-selective adsorption of small gas molecules such as N2, O2, H2, NO, and CH4, while the corresponding non-fluorinated complexes show no guest encapsulation.
AB - Fully fluorinated coordination complexes, [M(L)2] (M = Cu2+, Pd2+, Pt2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1:1 selective recognition of CO2 and metal ion-selective adsorption of small gas molecules such as N2, O2, H2, NO, and CH4, while the corresponding non-fluorinated complexes show no guest encapsulation.
UR - http://www.scopus.com/inward/record.url?scp=85032619400&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85032619400&partnerID=8YFLogxK
U2 - 10.1039/c7ce01413a
DO - 10.1039/c7ce01413a
M3 - Article
AN - SCOPUS:85032619400
VL - 19
SP - 6263
EP - 6266
JO - CrystEngComm
JF - CrystEngComm
SN - 1466-8033
IS - 42
ER -