Environmentally friendly electroorganic synthesis using solid-supported acids and bases

Toshiki Tajima, Toshio Fuchigami

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

We have successfully developed novel electrolytic systems using solid-supported acids and bases. Anodic fluorination of various compounds using KF as a fluorine source and solid-supported acids as a supporting electrolyte was successfully carried out to provide the corresponding fluorinated products in good to excellent yields. On the other hand, anodic methoxylation, anodic acetoxylation, Kolbe electrolysis, and non-Kolbe electrolysis of various compounds using solid-supported bases as a precursor of supporting electrolytes were also conducted to afford the corresponding methoxylated, acetoxylated, Kolbe, and non-Kolbe products in moderate to excellent yields, respectively.

Original languageEnglish
Pages (from-to)406-415
Number of pages10
JournalYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
Volume64
Issue number4
Publication statusPublished - 2006 Apr
Externally publishedYes

Fingerprint

Electrolysis
Electrolytes
Acids
Fluorination
Fluorine

Keywords

  • Anodic acetoxylation
  • Anodic fluorination
  • Anodic methoxylation
  • Green sustainable chemistry
  • Kolbe electrolysis
  • Non-Kolbe electrolysis
  • Potassium fluoride
  • Solid-supported acid
  • Solid-supported base
  • Supporting electrolyte

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Environmentally friendly electroorganic synthesis using solid-supported acids and bases. / Tajima, Toshiki; Fuchigami, Toshio.

In: Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, Vol. 64, No. 4, 04.2006, p. 406-415.

Research output: Contribution to journalArticle

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