Abstract
We have successfully developed novel electrolytic systems using solid-supported acids and bases. Anodic fluorination of various compounds using KF as a fluorine source and solid-supported acids as a supporting electrolyte was successfully carried out to provide the corresponding fluorinated products in good to excellent yields. On the other hand, anodic methoxylation, anodic acetoxylation, Kolbe electrolysis, and non-Kolbe electrolysis of various compounds using solid-supported bases as a precursor of supporting electrolytes were also conducted to afford the corresponding methoxylated, acetoxylated, Kolbe, and non-Kolbe products in moderate to excellent yields, respectively.
Original language | English |
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Pages (from-to) | 406-415 |
Number of pages | 10 |
Journal | Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry |
Volume | 64 |
Issue number | 4 |
DOIs | |
Publication status | Published - 2006 Apr |
Externally published | Yes |
Keywords
- Anodic acetoxylation
- Anodic fluorination
- Anodic methoxylation
- Green sustainable chemistry
- Kolbe electrolysis
- Non-Kolbe electrolysis
- Potassium fluoride
- Solid-supported acid
- Solid-supported base
- Supporting electrolyte
ASJC Scopus subject areas
- Organic Chemistry