Abstract
We have successfully developed novel electrolytic systems using solid-supported acids and bases. Anodic fluorination of various compounds using KF as a fluorine source and solid-supported acids as a supporting electrolyte was successfully carried out to provide the corresponding fluorinated products in good to excellent yields. On the other hand, anodic methoxylation, anodic acetoxylation, Kolbe electrolysis, and non-Kolbe electrolysis of various compounds using solid-supported bases as a precursor of supporting electrolytes were also conducted to afford the corresponding methoxylated, acetoxylated, Kolbe, and non-Kolbe products in moderate to excellent yields, respectively.
| Original language | English |
|---|---|
| Pages (from-to) | 406-415 |
| Number of pages | 10 |
| Journal | Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry |
| Volume | 64 |
| Issue number | 4 |
| Publication status | Published - 2006 Apr 1 |
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Keywords
- Anodic acetoxylation
- Anodic fluorination
- Anodic methoxylation
- Green sustainable chemistry
- Kolbe electrolysis
- Non-Kolbe electrolysis
- Potassium fluoride
- Solid-supported acid
- Solid-supported base
- Supporting electrolyte
ASJC Scopus subject areas
- Organic Chemistry
Cite this
Tajima, T., & Fuchigami, T. (2006). Environmentally friendly electroorganic synthesis using solid-supported acids and bases. Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, 64(4), 406-415.