Environmentally friendly electroorganic synthesis using solid-supported acids and bases

Toshiki Tajima; Toshio Fuchigami

doi:10.5059/yukigoseikyokaishi.64.406

Environmentally friendly electroorganic synthesis using solid-supported acids and bases

Toshiki Tajima, Toshio Fuchigami

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

We have successfully developed novel electrolytic systems using solid-supported acids and bases. Anodic fluorination of various compounds using KF as a fluorine source and solid-supported acids as a supporting electrolyte was successfully carried out to provide the corresponding fluorinated products in good to excellent yields. On the other hand, anodic methoxylation, anodic acetoxylation, Kolbe electrolysis, and non-Kolbe electrolysis of various compounds using solid-supported bases as a precursor of supporting electrolytes were also conducted to afford the corresponding methoxylated, acetoxylated, Kolbe, and non-Kolbe products in moderate to excellent yields, respectively.

Original language	English
Pages (from-to)	406-415
Number of pages	10
Journal	Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
Volume	64
Issue number	4
DOIs	https://doi.org/10.5059/yukigoseikyokaishi.64.406
Publication status	Published - 2006 Apr
Externally published	Yes

Keywords

Anodic acetoxylation
Anodic fluorination
Anodic methoxylation
Green sustainable chemistry
Kolbe electrolysis
Non-Kolbe electrolysis
Potassium fluoride
Solid-supported acid
Solid-supported base
Supporting electrolyte

ASJC Scopus subject areas

Organic Chemistry

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10.5059/yukigoseikyokaishi.64.406

Cite this

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title = "Environmentally friendly electroorganic synthesis using solid-supported acids and bases",

abstract = "We have successfully developed novel electrolytic systems using solid-supported acids and bases. Anodic fluorination of various compounds using KF as a fluorine source and solid-supported acids as a supporting electrolyte was successfully carried out to provide the corresponding fluorinated products in good to excellent yields. On the other hand, anodic methoxylation, anodic acetoxylation, Kolbe electrolysis, and non-Kolbe electrolysis of various compounds using solid-supported bases as a precursor of supporting electrolytes were also conducted to afford the corresponding methoxylated, acetoxylated, Kolbe, and non-Kolbe products in moderate to excellent yields, respectively.",

keywords = "Anodic acetoxylation, Anodic fluorination, Anodic methoxylation, Green sustainable chemistry, Kolbe electrolysis, Non-Kolbe electrolysis, Potassium fluoride, Solid-supported acid, Solid-supported base, Supporting electrolyte",

author = "Toshiki Tajima and Toshio Fuchigami",

year = "2006",

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doi = "10.5059/yukigoseikyokaishi.64.406",

language = "English",

volume = "64",

pages = "406--415",

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T1 - Environmentally friendly electroorganic synthesis using solid-supported acids and bases

AU - Tajima, Toshiki

AU - Fuchigami, Toshio

PY - 2006/4

Y1 - 2006/4

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AB - We have successfully developed novel electrolytic systems using solid-supported acids and bases. Anodic fluorination of various compounds using KF as a fluorine source and solid-supported acids as a supporting electrolyte was successfully carried out to provide the corresponding fluorinated products in good to excellent yields. On the other hand, anodic methoxylation, anodic acetoxylation, Kolbe electrolysis, and non-Kolbe electrolysis of various compounds using solid-supported bases as a precursor of supporting electrolytes were also conducted to afford the corresponding methoxylated, acetoxylated, Kolbe, and non-Kolbe products in moderate to excellent yields, respectively.

KW - Anodic acetoxylation

KW - Anodic fluorination

KW - Anodic methoxylation

KW - Green sustainable chemistry

KW - Kolbe electrolysis

KW - Non-Kolbe electrolysis

KW - Potassium fluoride

KW - Solid-supported acid

KW - Solid-supported base

KW - Supporting electrolyte

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JO - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry

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ER -

Environmentally friendly electroorganic synthesis using solid-supported acids and bases

Abstract

Keywords

ASJC Scopus subject areas

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