Abstract
We have successfully developed novel electrolytic systems using solid-supported acids and bases. Anodic fluorination of various compounds using KF as a fluorine source and solid-supported acids as a supporting electrolyte was successfully carried out to provide the corresponding fluorinated products in good to excellent yields. On the other hand, anodic methoxylation, anodic acetoxylation, Kolbe electrolysis, and non-Kolbe electrolysis of various compounds using solid-supported bases as a precursor of supporting electrolytes were also conducted to afford the corresponding methoxylated, acetoxylated, Kolbe, and non-Kolbe products in moderate to excellent yields, respectively.
| Original language | English |
|---|---|
| Pages (from-to) | 406-415 |
| Number of pages | 10 |
| Journal | Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry |
| Volume | 64 |
| Issue number | 4 |
| Publication status | Published - 2006 Apr |
| Externally published | Yes |
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Keywords
- Anodic acetoxylation
- Anodic fluorination
- Anodic methoxylation
- Green sustainable chemistry
- Kolbe electrolysis
- Non-Kolbe electrolysis
- Potassium fluoride
- Solid-supported acid
- Solid-supported base
- Supporting electrolyte
ASJC Scopus subject areas
- Organic Chemistry
Cite this
Environmentally friendly electroorganic synthesis using solid-supported acids and bases. / Tajima, Toshiki; Fuchigami, Toshio.
In: Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, Vol. 64, No. 4, 04.2006, p. 406-415.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Environmentally friendly electroorganic synthesis using solid-supported acids and bases
AU - Tajima, Toshiki
AU - Fuchigami, Toshio
PY - 2006/4
Y1 - 2006/4
N2 - We have successfully developed novel electrolytic systems using solid-supported acids and bases. Anodic fluorination of various compounds using KF as a fluorine source and solid-supported acids as a supporting electrolyte was successfully carried out to provide the corresponding fluorinated products in good to excellent yields. On the other hand, anodic methoxylation, anodic acetoxylation, Kolbe electrolysis, and non-Kolbe electrolysis of various compounds using solid-supported bases as a precursor of supporting electrolytes were also conducted to afford the corresponding methoxylated, acetoxylated, Kolbe, and non-Kolbe products in moderate to excellent yields, respectively.
AB - We have successfully developed novel electrolytic systems using solid-supported acids and bases. Anodic fluorination of various compounds using KF as a fluorine source and solid-supported acids as a supporting electrolyte was successfully carried out to provide the corresponding fluorinated products in good to excellent yields. On the other hand, anodic methoxylation, anodic acetoxylation, Kolbe electrolysis, and non-Kolbe electrolysis of various compounds using solid-supported bases as a precursor of supporting electrolytes were also conducted to afford the corresponding methoxylated, acetoxylated, Kolbe, and non-Kolbe products in moderate to excellent yields, respectively.
KW - Anodic acetoxylation
KW - Anodic fluorination
KW - Anodic methoxylation
KW - Green sustainable chemistry
KW - Kolbe electrolysis
KW - Non-Kolbe electrolysis
KW - Potassium fluoride
KW - Solid-supported acid
KW - Solid-supported base
KW - Supporting electrolyte
UR - http://www.scopus.com/inward/record.url?scp=33745271406&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33745271406&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:33745271406
VL - 64
SP - 406
EP - 415
JO - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
JF - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
SN - 0037-9980
IS - 4
ER -