Abstract
A potentiometric flow injection determination method for cationic polyelectrolytes utilizing a flow-through-type tetraphenylborate-selective electrode detector is described. The method is based on detecting any concentration decrease of the tetraphenylborate ion by the formation of an ion associate between cationic polyelectrolyte, poly(diallyl-dimethylammonium chloride) (Cat-floc) and tetraphenylborate ion. The response of the electrode detector, as a peak-shaped signal, was obtained for injected cationic polyelectrolyte samples. A linear relationship was found to exist between the peak height and the logarithmic concentration of Cat-floc with a slope of 17 mV/decade over a concentration range of 5 × 10-5 to 1 × 10-3 mol 1-1 . The detection limit for Cat-floc was 1 × 10-5 mol 1-1. The sampling rate was ca. 12 samples/h.
| Original language | English |
|---|---|
| Pages (from-to) | 515-518 |
| Number of pages | 4 |
| Journal | Bunseki Kagaku |
| Volume | 48 |
| Issue number | 5 |
| Publication status | Published - 1999 |
| Externally published | Yes |
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Keywords
- Cationic polyelectrolytes
- Flow injection analysis
- Ion associate
- Plasticized poly(vinyl chloride) membrane
- Tetraphenylborate-selective electrode
ASJC Scopus subject areas
- Analytical Chemistry
Cite this
Flow injection determination of cationic polyelectrolytes using a tetraphenylborate-selective electrode detector. / Masadome, Takashi; Asano, Yasukazu.
In: Bunseki Kagaku, Vol. 48, No. 5, 1999, p. 515-518.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Flow injection determination of cationic polyelectrolytes using a tetraphenylborate-selective electrode detector
AU - Masadome, Takashi
AU - Asano, Yasukazu
PY - 1999
Y1 - 1999
N2 - A potentiometric flow injection determination method for cationic polyelectrolytes utilizing a flow-through-type tetraphenylborate-selective electrode detector is described. The method is based on detecting any concentration decrease of the tetraphenylborate ion by the formation of an ion associate between cationic polyelectrolyte, poly(diallyl-dimethylammonium chloride) (Cat-floc) and tetraphenylborate ion. The response of the electrode detector, as a peak-shaped signal, was obtained for injected cationic polyelectrolyte samples. A linear relationship was found to exist between the peak height and the logarithmic concentration of Cat-floc with a slope of 17 mV/decade over a concentration range of 5 × 10-5 to 1 × 10-3 mol 1-1 . The detection limit for Cat-floc was 1 × 10-5 mol 1-1. The sampling rate was ca. 12 samples/h.
AB - A potentiometric flow injection determination method for cationic polyelectrolytes utilizing a flow-through-type tetraphenylborate-selective electrode detector is described. The method is based on detecting any concentration decrease of the tetraphenylborate ion by the formation of an ion associate between cationic polyelectrolyte, poly(diallyl-dimethylammonium chloride) (Cat-floc) and tetraphenylborate ion. The response of the electrode detector, as a peak-shaped signal, was obtained for injected cationic polyelectrolyte samples. A linear relationship was found to exist between the peak height and the logarithmic concentration of Cat-floc with a slope of 17 mV/decade over a concentration range of 5 × 10-5 to 1 × 10-3 mol 1-1 . The detection limit for Cat-floc was 1 × 10-5 mol 1-1. The sampling rate was ca. 12 samples/h.
KW - Cationic polyelectrolytes
KW - Flow injection analysis
KW - Ion associate
KW - Plasticized poly(vinyl chloride) membrane
KW - Tetraphenylborate-selective electrode
UR - http://www.scopus.com/inward/record.url?scp=0033457624&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0033457624&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0033457624
VL - 48
SP - 515
EP - 518
JO - Bunseki Kagaku
JF - Bunseki Kagaku
SN - 0525-1931
IS - 5
ER -