Flow injection determination of iodide ion in a photographic developing solution using iodide ion-selective electrode detector

Takashi Masadome, Risa Sonoda, Yasukazu Asano

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

A potentiometric flow injection determination method for iodide ion in a photographic developing solution was proposed by utilizing a flow-through type iodide ion-selective electrode detector. The sensing membrane of the electrode was Ag2S-AgI membrane. The response of the electrode detector as a peak-shape signal was obtained for injected iodide ion in a photographic developing solution. A linear relationship in the subnernstian zone was found to exist between peak height and the concentration of the iodide ion in a photographic developing solution in a concentration range from 0 to 6.0 x 10-5 mol l-1. The relative standard deviation for ten injections of 2 x 10-5 mol l-1 iodide ion in a photographic developing solution was 0.96% and the sampling rate was approximately 12-13 samples h-1. The iodide ion could be determined under coexisting of an organic reducing reagent and inorganic electrolytes of high concentration in a photographic developing solution sample solution by the present method. (C) 2000 Elsevier Science B.V.

Original languageEnglish
Pages (from-to)1123-1130
Number of pages8
JournalTalanta
Volume52
Issue number6
DOIs
Publication statusPublished - 2000 Sep 5

Keywords

  • Flow injection analysis
  • Iodide ion
  • Iodide-selective electrode detector
  • Photographic developing solution

ASJC Scopus subject areas

  • Analytical Chemistry

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