Formation of racemic crystals of transition metal complexes by grinding 1

1 Mixtures of enantiomeric crystals

Asao Nakamura, Tomohiro Sato, Reiko Kuroda

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Grinding a 1:1 enantiomeric mixture of chiral transition metal complex crystals and subsequent annealing afforded crystals of a racemic compound by diffusion and rearrangement of component molecules, without melting and without racemization of each enantiomeric species.

Original languageEnglish
Pages (from-to)2858-2859
Number of pages2
JournalChemical Communications
Issue number24
DOIs
Publication statusPublished - 2004 Dec 21
Externally publishedYes

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Coordination Complexes
Metal complexes
Transition metals
Crystals
Melting
Annealing
Molecules

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Formation of racemic crystals of transition metal complexes by grinding 1 : 1 Mixtures of enantiomeric crystals. / Nakamura, Asao; Sato, Tomohiro; Kuroda, Reiko.

In: Chemical Communications, No. 24, 21.12.2004, p. 2858-2859.

Research output: Contribution to journalArticle

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