Abstract
Two different coordination types of fully fluorinated dinuclear metal complexes, [Fe2L4(OMe)2] and [M2L4(OH2)2] (M = Co2+, Ni2+ and HL = bis(pentafluorobenzoyl)methane), were obtained. All of the complexes form non-porous crystals, which act as hosts for the adsorption of various benzene derivatives, e.g., benzene, toluene, p-xylene, anisole, and small gas molecules, e.g., CO2, O2, and NO. The complex of iron selectively adsorbs NO in high amounts and the complex of cobalt is found to store adsorbed O2.
| Original language | English |
|---|---|
| Pages (from-to) | 9062-9066 |
| Number of pages | 5 |
| Journal | Dalton Transactions |
| Volume | 48 |
| Issue number | 25 |
| DOIs | |
| Publication status | Published - 2019 Jan 1 |
ASJC Scopus subject areas
- Inorganic Chemistry
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Gonda, R., Rzeznicka, I. I., Kinoshita, Y., Uchida, S., & Hori, A. (2019). Guest encapsulations in non-porous crystals of fully fluorinated dinuclear metal complexes with the M2O2 core (M = Fe3+, Co2+, Ni2+). Dalton Transactions, 48(25), 9062-9066. https://doi.org/10.1039/c9dt01380f