TY - JOUR
T1 - Guest encapsulations in non-porous crystals of fully fluorinated dinuclear metal complexes with the M2O2 core (M = Fe3+, Co2+, Ni2+)
AU - Gonda, Ryu
AU - Rzeznicka, Izabela I.
AU - Kinoshita, Yuki
AU - Uchida, Sayaka
AU - Hori, Akiko
N1 - Funding Information:
This work was supported by Grant-in-Aid for Scientific Research C (no. 18K05153) of the JSPS KAKENHI.
Publisher Copyright:
© 2019 The Royal Society of Chemistry.
PY - 2019
Y1 - 2019
N2 - Two different coordination types of fully fluorinated dinuclear metal complexes, [Fe2L4(OMe)2] and [M2L4(OH2)2] (M = Co2+, Ni2+ and HL = bis(pentafluorobenzoyl)methane), were obtained. All of the complexes form non-porous crystals, which act as hosts for the adsorption of various benzene derivatives, e.g., benzene, toluene, p-xylene, anisole, and small gas molecules, e.g., CO2, O2, and NO. The complex of iron selectively adsorbs NO in high amounts and the complex of cobalt is found to store adsorbed O2.
AB - Two different coordination types of fully fluorinated dinuclear metal complexes, [Fe2L4(OMe)2] and [M2L4(OH2)2] (M = Co2+, Ni2+ and HL = bis(pentafluorobenzoyl)methane), were obtained. All of the complexes form non-porous crystals, which act as hosts for the adsorption of various benzene derivatives, e.g., benzene, toluene, p-xylene, anisole, and small gas molecules, e.g., CO2, O2, and NO. The complex of iron selectively adsorbs NO in high amounts and the complex of cobalt is found to store adsorbed O2.
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U2 - 10.1039/c9dt01380f
DO - 10.1039/c9dt01380f
M3 - Article
C2 - 31161178
AN - SCOPUS:85068156308
VL - 48
SP - 9062
EP - 9066
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 25
ER -