Abstract
Two different coordination types of fully fluorinated dinuclear metal complexes, [Fe2L4(OMe)2] and [M2L4(OH2)2] (M = Co2+, Ni2+ and HL = bis(pentafluorobenzoyl)methane), were obtained. All of the complexes form non-porous crystals, which act as hosts for the adsorption of various benzene derivatives, e.g., benzene, toluene, p-xylene, anisole, and small gas molecules, e.g., CO2, O2, and NO. The complex of iron selectively adsorbs NO in high amounts and the complex of cobalt is found to store adsorbed O2.
| Original language | English |
|---|---|
| Pages (from-to) | 9062-9066 |
| Number of pages | 5 |
| Journal | Dalton Transactions |
| Volume | 48 |
| Issue number | 25 |
| DOIs | |
| Publication status | Published - 2019 Jan 1 |
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ASJC Scopus subject areas
- Inorganic Chemistry
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Guest encapsulations in non-porous crystals of fully fluorinated dinuclear metal complexes with the M2O2 core (M = Fe3+, Co2+, Ni2+). / Gonda, Ryu; Rzeznicka, Izabela Irena; Kinoshita, Yuki; Uchida, Sayaka; Hori, Akiko.
In: Dalton Transactions, Vol. 48, No. 25, 01.01.2019, p. 9062-9066.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Guest encapsulations in non-porous crystals of fully fluorinated dinuclear metal complexes with the M2O2 core (M = Fe3+, Co2+, Ni2+)
AU - Gonda, Ryu
AU - Rzeznicka, Izabela Irena
AU - Kinoshita, Yuki
AU - Uchida, Sayaka
AU - Hori, Akiko
PY - 2019/1/1
Y1 - 2019/1/1
N2 - Two different coordination types of fully fluorinated dinuclear metal complexes, [Fe2L4(OMe)2] and [M2L4(OH2)2] (M = Co2+, Ni2+ and HL = bis(pentafluorobenzoyl)methane), were obtained. All of the complexes form non-porous crystals, which act as hosts for the adsorption of various benzene derivatives, e.g., benzene, toluene, p-xylene, anisole, and small gas molecules, e.g., CO2, O2, and NO. The complex of iron selectively adsorbs NO in high amounts and the complex of cobalt is found to store adsorbed O2.
AB - Two different coordination types of fully fluorinated dinuclear metal complexes, [Fe2L4(OMe)2] and [M2L4(OH2)2] (M = Co2+, Ni2+ and HL = bis(pentafluorobenzoyl)methane), were obtained. All of the complexes form non-porous crystals, which act as hosts for the adsorption of various benzene derivatives, e.g., benzene, toluene, p-xylene, anisole, and small gas molecules, e.g., CO2, O2, and NO. The complex of iron selectively adsorbs NO in high amounts and the complex of cobalt is found to store adsorbed O2.
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U2 - 10.1039/c9dt01380f
DO - 10.1039/c9dt01380f
M3 - Article
VL - 48
SP - 9062
EP - 9066
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 25
ER -