Guest encapsulations in non-porous crystals of fully fluorinated dinuclear metal complexes with the M2O2 core (M = Fe3+, Co2+, Ni2+)

Ryu Gonda, Izabela Irena Rzeznicka, Yuki Kinoshita, Sayaka Uchida, Akiko Hori

Research output: Contribution to journalArticle

Abstract

Two different coordination types of fully fluorinated dinuclear metal complexes, [Fe2L4(OMe)2] and [M2L4(OH2)2] (M = Co2+, Ni2+ and HL = bis(pentafluorobenzoyl)methane), were obtained. All of the complexes form non-porous crystals, which act as hosts for the adsorption of various benzene derivatives, e.g., benzene, toluene, p-xylene, anisole, and small gas molecules, e.g., CO2, O2, and NO. The complex of iron selectively adsorbs NO in high amounts and the complex of cobalt is found to store adsorbed O2.

Original languageEnglish
Pages (from-to)9062-9066
Number of pages5
JournalDalton Transactions
Volume48
Issue number25
DOIs
Publication statusPublished - 2019 Jan 1

Fingerprint

Benzene Derivatives
Coordination Complexes
Methane
Toluene
Cobalt
Benzene
Encapsulation
Iron
Gases
Adsorption
Crystals
Molecules
4-xylene
anisole

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Guest encapsulations in non-porous crystals of fully fluorinated dinuclear metal complexes with the M2O2 core (M = Fe3+, Co2+, Ni2+). / Gonda, Ryu; Rzeznicka, Izabela Irena; Kinoshita, Yuki; Uchida, Sayaka; Hori, Akiko.

In: Dalton Transactions, Vol. 48, No. 25, 01.01.2019, p. 9062-9066.

Research output: Contribution to journalArticle

@article{d95106f698e545db874d1e0fd4b7c86a,
title = "Guest encapsulations in non-porous crystals of fully fluorinated dinuclear metal complexes with the M2O2 core (M = Fe3+, Co2+, Ni2+)",
abstract = "Two different coordination types of fully fluorinated dinuclear metal complexes, [Fe2L4(OMe)2] and [M2L4(OH2)2] (M = Co2+, Ni2+ and HL = bis(pentafluorobenzoyl)methane), were obtained. All of the complexes form non-porous crystals, which act as hosts for the adsorption of various benzene derivatives, e.g., benzene, toluene, p-xylene, anisole, and small gas molecules, e.g., CO2, O2, and NO. The complex of iron selectively adsorbs NO in high amounts and the complex of cobalt is found to store adsorbed O2.",
author = "Ryu Gonda and Rzeznicka, {Izabela Irena} and Yuki Kinoshita and Sayaka Uchida and Akiko Hori",
year = "2019",
month = "1",
day = "1",
doi = "10.1039/c9dt01380f",
language = "English",
volume = "48",
pages = "9062--9066",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "25",

}

TY - JOUR

T1 - Guest encapsulations in non-porous crystals of fully fluorinated dinuclear metal complexes with the M2O2 core (M = Fe3+, Co2+, Ni2+)

AU - Gonda, Ryu

AU - Rzeznicka, Izabela Irena

AU - Kinoshita, Yuki

AU - Uchida, Sayaka

AU - Hori, Akiko

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Two different coordination types of fully fluorinated dinuclear metal complexes, [Fe2L4(OMe)2] and [M2L4(OH2)2] (M = Co2+, Ni2+ and HL = bis(pentafluorobenzoyl)methane), were obtained. All of the complexes form non-porous crystals, which act as hosts for the adsorption of various benzene derivatives, e.g., benzene, toluene, p-xylene, anisole, and small gas molecules, e.g., CO2, O2, and NO. The complex of iron selectively adsorbs NO in high amounts and the complex of cobalt is found to store adsorbed O2.

AB - Two different coordination types of fully fluorinated dinuclear metal complexes, [Fe2L4(OMe)2] and [M2L4(OH2)2] (M = Co2+, Ni2+ and HL = bis(pentafluorobenzoyl)methane), were obtained. All of the complexes form non-porous crystals, which act as hosts for the adsorption of various benzene derivatives, e.g., benzene, toluene, p-xylene, anisole, and small gas molecules, e.g., CO2, O2, and NO. The complex of iron selectively adsorbs NO in high amounts and the complex of cobalt is found to store adsorbed O2.

UR - http://www.scopus.com/inward/record.url?scp=85068156308&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85068156308&partnerID=8YFLogxK

U2 - 10.1039/c9dt01380f

DO - 10.1039/c9dt01380f

M3 - Article

VL - 48

SP - 9062

EP - 9066

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 25

ER -