Guest encapsulations in non-porous crystals of fully fluorinated dinuclear metal complexes with the M2O2 core (M = Fe3+, Co2+, Ni2+)

Ryu Gonda, Izabela Irena Rzeznicka, Yuki Kinoshita, Sayaka Uchida, Akiko Hori

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

Two different coordination types of fully fluorinated dinuclear metal complexes, [Fe2L4(OMe)2] and [M2L4(OH2)2] (M = Co2+, Ni2+ and HL = bis(pentafluorobenzoyl)methane), were obtained. All of the complexes form non-porous crystals, which act as hosts for the adsorption of various benzene derivatives, e.g., benzene, toluene, p-xylene, anisole, and small gas molecules, e.g., CO2, O2, and NO. The complex of iron selectively adsorbs NO in high amounts and the complex of cobalt is found to store adsorbed O2.

Original languageEnglish
Pages (from-to)9062-9066
Number of pages5
JournalDalton Transactions
Volume48
Issue number25
DOIs
Publication statusPublished - 2019 Jan 1

ASJC Scopus subject areas

  • Inorganic Chemistry

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