Hydrogenation reaction of Co3Ti alloy under high pressure and high temperature

Hiroyuki Saitoh, Masahiro Morimoto, Tetsu Watanuki, Toyoto Sato, Shigeyuki Takagi, Shin ichi Orimo

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

To synthesize a novel titanium-containing hydride, a Co3Ti alloy with a Cu3Au-type structure was hydrogenated at 9 GPa and 900 °C. Structural changes under high pressure were monitored via in situ synchrotron radiation x-ray diffraction at BL14B1, SPring-8. The in-situ measurement reveals that novel hydride Co3TiH~4 is formed at 9 GPa and 900 °C. When the sample was depressurized at room temperature, the formed hydride decomposed to (the previously reported) Co3TiH~1 at a pressure of ~1 GPa. Co3TiH~1 was recovered at ambient conditions and decomposed gradually into the Co3Ti alloy. Co3TiH~4 is thermodynamically stable only at pressures above 1 GPa.

Original languageEnglish
Pages (from-to)33675-33680
Number of pages6
JournalInternational Journal of Hydrogen Energy
Volume45
Issue number58
DOIs
Publication statusPublished - 2020 Nov 27
Externally publishedYes

Keywords

  • CoTiH
  • High pressure
  • Hydride
  • Synchrotron radiation x-ray

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

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