Indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids

Atsushi Nakajima, Yuta Doi, Toshio Fuchigami, Toshiki Tajima

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

We have developed a novel electrolytic system for indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids. It was demonstrated that hydrogen halides derived from the cation exchange reaction act as not only a supporting electrolyte but also a mediator in acetonitrile. On the basis of the electrolytic system, indirect anodic oxidation of various benzyl alcohols in the presence of 2,6-lutidine was successfully achieved by controlled potential electrolysis to provide the corresponding benzaldehydes in good to excellent yields.

Original languageEnglish
Pages (from-to)177-180
Number of pages4
JournalJournal of Electroanalytical Chemistry
Volume623
Issue number2
DOIs
Publication statusPublished - 2008 Nov 15
Externally publishedYes

Fingerprint

Alkaline Earth Metals
Metal halides
Alkaline earth metals
Anodic oxidation
Cations
Benzyl Alcohols
Ion exchange
Benzaldehydes
Positive ions
Acids
Acetonitrile
Electrolysis
Electrolytes
Hydrogen
Alcohols

Keywords

  • Alkaline (earth) metal halide
  • Cation exchange reaction
  • Indirect anodic oxidation
  • Mediator
  • Solid-supported acid

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Analytical Chemistry
  • Electrochemistry

Cite this

Indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids. / Nakajima, Atsushi; Doi, Yuta; Fuchigami, Toshio; Tajima, Toshiki.

In: Journal of Electroanalytical Chemistry, Vol. 623, No. 2, 15.11.2008, p. 177-180.

Research output: Contribution to journalArticle

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