Abstract
We have developed a novel electrolytic system for indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids. It was demonstrated that hydrogen halides derived from the cation exchange reaction act as not only a supporting electrolyte but also a mediator in acetonitrile. On the basis of the electrolytic system, indirect anodic oxidation of various benzyl alcohols in the presence of 2,6-lutidine was successfully achieved by controlled potential electrolysis to provide the corresponding benzaldehydes in good to excellent yields.
| Original language | English |
|---|---|
| Pages (from-to) | 177-180 |
| Number of pages | 4 |
| Journal | Journal of Electroanalytical Chemistry |
| Volume | 623 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 2008 Nov 15 |
| Externally published | Yes |
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Keywords
- Alkaline (earth) metal halide
- Cation exchange reaction
- Indirect anodic oxidation
- Mediator
- Solid-supported acid
ASJC Scopus subject areas
- Chemical Engineering(all)
- Analytical Chemistry
- Electrochemistry
Cite this
Indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids. / Nakajima, Atsushi; Doi, Yuta; Fuchigami, Toshio; Tajima, Toshiki.
In: Journal of Electroanalytical Chemistry, Vol. 623, No. 2, 15.11.2008, p. 177-180.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids
AU - Nakajima, Atsushi
AU - Doi, Yuta
AU - Fuchigami, Toshio
AU - Tajima, Toshiki
PY - 2008/11/15
Y1 - 2008/11/15
N2 - We have developed a novel electrolytic system for indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids. It was demonstrated that hydrogen halides derived from the cation exchange reaction act as not only a supporting electrolyte but also a mediator in acetonitrile. On the basis of the electrolytic system, indirect anodic oxidation of various benzyl alcohols in the presence of 2,6-lutidine was successfully achieved by controlled potential electrolysis to provide the corresponding benzaldehydes in good to excellent yields.
AB - We have developed a novel electrolytic system for indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids. It was demonstrated that hydrogen halides derived from the cation exchange reaction act as not only a supporting electrolyte but also a mediator in acetonitrile. On the basis of the electrolytic system, indirect anodic oxidation of various benzyl alcohols in the presence of 2,6-lutidine was successfully achieved by controlled potential electrolysis to provide the corresponding benzaldehydes in good to excellent yields.
KW - Alkaline (earth) metal halide
KW - Cation exchange reaction
KW - Indirect anodic oxidation
KW - Mediator
KW - Solid-supported acid
UR - http://www.scopus.com/inward/record.url?scp=54449101228&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=54449101228&partnerID=8YFLogxK
U2 - 10.1016/j.jelechem.2008.07.009
DO - 10.1016/j.jelechem.2008.07.009
M3 - Article
VL - 623
SP - 177
EP - 180
JO - Journal of Electroanalytical Chemistry
JF - Journal of Electroanalytical Chemistry
SN - 0022-0728
IS - 2
ER -