Indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids

Atsushi Nakajima; Yuta Doi; Toshio Fuchigami; Toshiki Tajima

doi:10.1016/j.jelechem.2008.07.009

Indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids

Atsushi Nakajima, Yuta Doi, Toshio Fuchigami, Toshiki Tajima

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

We have developed a novel electrolytic system for indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids. It was demonstrated that hydrogen halides derived from the cation exchange reaction act as not only a supporting electrolyte but also a mediator in acetonitrile. On the basis of the electrolytic system, indirect anodic oxidation of various benzyl alcohols in the presence of 2,6-lutidine was successfully achieved by controlled potential electrolysis to provide the corresponding benzaldehydes in good to excellent yields.

Original language	English
Pages (from-to)	177-180
Number of pages	4
Journal	Journal of Electroanalytical Chemistry
Volume	623
Issue number	2
DOIs	https://doi.org/10.1016/j.jelechem.2008.07.009
Publication status	Published - 2008 Nov 15
Externally published	Yes

Keywords

Alkaline (earth) metal halide
Cation exchange reaction
Indirect anodic oxidation
Mediator
Solid-supported acid

ASJC Scopus subject areas

Analytical Chemistry
Chemical Engineering(all)
Electrochemistry

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10.1016/j.jelechem.2008.07.009

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title = "Indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids",

abstract = "We have developed a novel electrolytic system for indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids. It was demonstrated that hydrogen halides derived from the cation exchange reaction act as not only a supporting electrolyte but also a mediator in acetonitrile. On the basis of the electrolytic system, indirect anodic oxidation of various benzyl alcohols in the presence of 2,6-lutidine was successfully achieved by controlled potential electrolysis to provide the corresponding benzaldehydes in good to excellent yields.",

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T1 - Indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids

AU - Nakajima, Atsushi

AU - Doi, Yuta

AU - Fuchigami, Toshio

AU - Tajima, Toshiki

PY - 2008/11/15

Y1 - 2008/11/15

N2 - We have developed a novel electrolytic system for indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids. It was demonstrated that hydrogen halides derived from the cation exchange reaction act as not only a supporting electrolyte but also a mediator in acetonitrile. On the basis of the electrolytic system, indirect anodic oxidation of various benzyl alcohols in the presence of 2,6-lutidine was successfully achieved by controlled potential electrolysis to provide the corresponding benzaldehydes in good to excellent yields.

AB - We have developed a novel electrolytic system for indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids. It was demonstrated that hydrogen halides derived from the cation exchange reaction act as not only a supporting electrolyte but also a mediator in acetonitrile. On the basis of the electrolytic system, indirect anodic oxidation of various benzyl alcohols in the presence of 2,6-lutidine was successfully achieved by controlled potential electrolysis to provide the corresponding benzaldehydes in good to excellent yields.

KW - Alkaline (earth) metal halide

KW - Cation exchange reaction

KW - Indirect anodic oxidation

KW - Mediator

KW - Solid-supported acid

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