Intramolecular carbostannation reaction of active methine compounds with an unactivated C-C π-bond mediated by SnCl4-Et3N

O. Kitagawa; H. Fujiwara; T. Suzuki; T. Taguchi; M. Shiro

doi:10.1021/jo000784z

Intramolecular carbostannation reaction of active methine compounds with an unactivated C-C π-bond mediated by SnCl₄-Et₃N

O. Kitagawa, H. Fujiwara, T. Suzuki, T. Taguchi, M. Shiro

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

In the presence of SnCl₄ and Et₃N, intramolecular carbostannation reaction of various active methine compounds having an 'unactivated alkenyl, alkynyl, or allenyl group proceeds in good yields with complete regioselectivity. The subsequent reaction of the resulting Sn intermediates with some electrophiles provides functionalized cyclopentane and cyclohexane derivatives.

Original language	English
Pages (from-to)	6819-6825
Number of pages	7
Journal	Journal of Organic Chemistry
Volume	65
Issue number	21
DOIs	https://doi.org/10.1021/jo000784z
Publication status	Published - 2000 Oct 20
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1021/jo000784z

Cite this

@article{383fb71e5a4e4e25916901d8729934fe,

title = "Intramolecular carbostannation reaction of active methine compounds with an unactivated C-C π-bond mediated by SnCl4-Et3N",

abstract = "In the presence of SnCl4 and Et3N, intramolecular carbostannation reaction of various active methine compounds having an 'unactivated alkenyl, alkynyl, or allenyl group proceeds in good yields with complete regioselectivity. The subsequent reaction of the resulting Sn intermediates with some electrophiles provides functionalized cyclopentane and cyclohexane derivatives.",

author = "O. Kitagawa and H. Fujiwara and T. Suzuki and T. Taguchi and M. Shiro",

year = "2000",

month = oct,

day = "20",

doi = "10.1021/jo000784z",

language = "English",

volume = "65",

pages = "6819--6825",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - Intramolecular carbostannation reaction of active methine compounds with an unactivated C-C π-bond mediated by SnCl4-Et3N

AU - Kitagawa, O.

AU - Fujiwara, H.

AU - Suzuki, T.

AU - Taguchi, T.

AU - Shiro, M.

PY - 2000/10/20

Y1 - 2000/10/20

N2 - In the presence of SnCl4 and Et3N, intramolecular carbostannation reaction of various active methine compounds having an 'unactivated alkenyl, alkynyl, or allenyl group proceeds in good yields with complete regioselectivity. The subsequent reaction of the resulting Sn intermediates with some electrophiles provides functionalized cyclopentane and cyclohexane derivatives.

AB - In the presence of SnCl4 and Et3N, intramolecular carbostannation reaction of various active methine compounds having an 'unactivated alkenyl, alkynyl, or allenyl group proceeds in good yields with complete regioselectivity. The subsequent reaction of the resulting Sn intermediates with some electrophiles provides functionalized cyclopentane and cyclohexane derivatives.

UR - http://www.scopus.com/inward/record.url?scp=0034693301&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034693301&partnerID=8YFLogxK

U2 - 10.1021/jo000784z

DO - 10.1021/jo000784z

M3 - Article

AN - SCOPUS:0034693301

SN - 0022-3263

VL - 65

SP - 6819

EP - 6825

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 21

ER -

Intramolecular carbostannation reaction of active methine compounds with an unactivated C-C π-bond mediated by SnCl₄-Et₃N

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this