Intramolecular carbostannation reaction of active methine compounds with an unactivated C-C π-bond mediated by SnCl4-Et3N

O. Kitagawa, H. Fujiwara, T. Suzuki, T. Taguchi, M. Shiro

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

In the presence of SnCl4 and Et3N, intramolecular carbostannation reaction of various active methine compounds having an 'unactivated alkenyl, alkynyl, or allenyl group proceeds in good yields with complete regioselectivity. The subsequent reaction of the resulting Sn intermediates with some electrophiles provides functionalized cyclopentane and cyclohexane derivatives.

Original languageEnglish
Pages (from-to)6819-6825
Number of pages7
JournalJournal of Organic Chemistry
Volume65
Issue number21
DOIs
Publication statusPublished - 2000 Oct 20
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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