Ionic iodocarbocyclization reaction

Osamu Kitagawa, Tadashi Inoue, Takeo Taguchi

Research output: Contribution to journalArticlepeer-review

35 Citations (Scopus)

Abstract

Iodocarbocyclization reactions of dimethyl alkenylmalonates in the presence of I2 and Ti(Ot-Bu)4 proceed in a regioselective and stereospecific manner through an ionic mechanism.

Original languageEnglish
Pages (from-to)2167-2170
Number of pages4
JournalTetrahedron Letters
Volume33
Issue number16
DOIs
Publication statusPublished - 1992 Apr 14
Externally publishedYes

Keywords

  • alkenylmalonate
  • cyclopentane derivative
  • iodine
  • iodocarbocyclization
  • γ-butyrolactone

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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