Mechanical alloying of the Ti-Al system in atmosphere of hydrogen and argon

Akito Takasaki, Yoshio Furuya

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Three kinds of Ti-Al powders, Ti72Al28, Ti57Al43 and Ti48Al52, were mechanically alloyed by a planetary ball mill in atmosphere of argon or hydrogen gases (0.1 MPa) with alloying times up to 30 h. The mechanical alloying (MA) process as well as the phase variations of each powder after subsequent heating at 1173 K were investigated. About 5000 wppm hydrogen, which could be easily removed by a heat treatment at 800 K (heating rate was 20 K/min), was occluded in all powders during MA in the hydrogen atmosphere, whereas the mechanically alloyed powders in the argon atmosphere occluded about 1000 wppm hydrogen. In the hydrogen atmosphere, the titanium powder easily crumbled into finer particles, assisting the diffusion of aluminum into titanium (solid-solid reaction) at an early stage of the MA process and accelerating the formation of an amorphous-like phase at a longer MA process. The phase formation after heat treatment of MA powders at 1173 K could be estimated by the Ti-Al binary phase diagram without the effect of the gas atmosphere.

Original languageEnglish
Pages (from-to)1205-1217
Number of pages13
JournalNanostructured Materials
Volume11
Issue number8
DOIs
Publication statusPublished - 1999 Nov
Externally publishedYes

Fingerprint

Argon
Mechanical alloying
Powders
alloying
Hydrogen
argon
atmospheres
hydrogen
Titanium
heat treatment
titanium
Gases
Heat treatment
heating
Ball mills
heat of formation
Aluminum
Heating rate
Alloying
gases

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Mechanical alloying of the Ti-Al system in atmosphere of hydrogen and argon. / Takasaki, Akito; Furuya, Yoshio.

In: Nanostructured Materials, Vol. 11, No. 8, 11.1999, p. 1205-1217.

Research output: Contribution to journalArticle

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