Multi-directional N2 desorption in N2O decomposition on Rh(1 1 0)

Kenji Imamura; Hideyuki Horino; Izabela Rzeźnicka; Ivan Kobal; Anton Kokalj; Yuichi Ohno; Bernard E. Nieuwenhuys; Atsuko Hiratsuka; Tatsuo Matsushima

doi:10.1016/j.susc.2004.06.054

Multi-directional N₂ desorption in N₂O decomposition on Rh(1 1 0)

Kenji Imamura, Hideyuki Horino, Izabela Rzeźnicka, Ivan Kobal, Anton Kokalj, Yuichi Ohno, Bernard E. Nieuwenhuys, Atsuko Hiratsuka, Tatsuo Matsushima

Research output: Contribution to journal › Conference article › peer-review

24 Citations (Scopus)

Abstract

The angular distribution of desorbing N₂ was studied in the decomposition of N₂O(a) on Rh(1 1 0) at 50-200 K with angle-resolved thermal desorption. N₂ desorption showed five peaks at around 70 K (β₅-N₂), 95 K (β₄-N₂), 115 K (β₃-N₂), 140 K (β₂-N₂), and 160 K (β₁-N₂). β₁-N₂ yielded a cosine distribution, whereas the others involved desorption components that collimated at either 69±3° or 27±3° off normal into the [0 0 1] direction. The 27° component was suppressed on clean (1×1) facets. The 69° component is proposed to be due to decomposition of N ₂O oriented in the [0 0 1] direction.

Original language	English
Pages (from-to)	1076-1081
Number of pages	6
Journal	Surface Science
Volume	566-568
Issue number	1-3 PART 2
DOIs	https://doi.org/10.1016/j.susc.2004.06.054
Publication status	Published - 2004 Sept 20
Externally published	Yes
Event	Proceedings of the 22nd European Conference on Surface Science - Prague, Czech Republic Duration: 2003 Sept 7 → 2003 Sept 12

Keywords

Angle resolved DIET (including electron stimulated desorption ion angular distribution (ESDIAD))
Catalysis
Nitrogen oxides
Rhodium
Surface chemical reaction
Thermal desorption

ASJC Scopus subject areas

Condensed Matter Physics
Surfaces and Interfaces
Surfaces, Coatings and Films
Materials Chemistry

Access to Document

10.1016/j.susc.2004.06.054

Cite this

@article{482aab9ae5e443a1a97c8562f96c2a7d,

title = "Multi-directional N2 desorption in N2O decomposition on Rh(1 1 0)",

abstract = "The angular distribution of desorbing N2 was studied in the decomposition of N2O(a) on Rh(1 1 0) at 50-200 K with angle-resolved thermal desorption. N2 desorption showed five peaks at around 70 K (β5-N2), 95 K (β4-N2), 115 K (β3-N2), 140 K (β2-N2), and 160 K (β1-N2). β1-N2 yielded a cosine distribution, whereas the others involved desorption components that collimated at either 69±3° or 27±3° off normal into the [0 0 1] direction. The 27° component was suppressed on clean (1×1) facets. The 69° component is proposed to be due to decomposition of N 2O oriented in the [0 0 1] direction.",

keywords = "Angle resolved DIET (including electron stimulated desorption ion angular distribution (ESDIAD)), Catalysis, Nitrogen oxides, Rhodium, Surface chemical reaction, Thermal desorption",

author = "Kenji Imamura and Hideyuki Horino and Izabela Rze{\'z}nicka and Ivan Kobal and Anton Kokalj and Yuichi Ohno and Nieuwenhuys, {Bernard E.} and Atsuko Hiratsuka and Tatsuo Matsushima",

note = "Funding Information: Izabela Rze{\'z}nicka is indebted to the Ministry of Education, Science, Sports and Culture of Japan for 2000–2004 scholarship. Anton Kokalj and Ivan Kobal were supported by the scientist exchange program between the Japanese Society for the Promotion of Science (JSPS) and the Ministry of Education, Science, and Sports of Slovenia in 2002–2003. Bernard E. Nieuwenhuys is indebted to Hokkaido University for the visiting professorship in 2002. This work was partly supported by Grant-in-Aid No. 13640493 for General Scientific Research from JSPS.; Proceedings of the 22nd European Conference on Surface Science ; Conference date: 07-09-2003 Through 12-09-2003",

year = "2004",

month = sep,

day = "20",

doi = "10.1016/j.susc.2004.06.054",

language = "English",

volume = "566-568",

pages = "1076--1081",

journal = "Surface Science",

issn = "0039-6028",

publisher = "Elsevier",

number = "1-3 PART 2",

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TY - JOUR

T1 - Multi-directional N2 desorption in N2O decomposition on Rh(1 1 0)

AU - Imamura, Kenji

AU - Horino, Hideyuki

AU - Rzeźnicka, Izabela

AU - Kobal, Ivan

AU - Kokalj, Anton

AU - Ohno, Yuichi

AU - Nieuwenhuys, Bernard E.

AU - Hiratsuka, Atsuko

AU - Matsushima, Tatsuo

N1 - Funding Information: Izabela Rzeźnicka is indebted to the Ministry of Education, Science, Sports and Culture of Japan for 2000–2004 scholarship. Anton Kokalj and Ivan Kobal were supported by the scientist exchange program between the Japanese Society for the Promotion of Science (JSPS) and the Ministry of Education, Science, and Sports of Slovenia in 2002–2003. Bernard E. Nieuwenhuys is indebted to Hokkaido University for the visiting professorship in 2002. This work was partly supported by Grant-in-Aid No. 13640493 for General Scientific Research from JSPS.

PY - 2004/9/20

Y1 - 2004/9/20

N2 - The angular distribution of desorbing N2 was studied in the decomposition of N2O(a) on Rh(1 1 0) at 50-200 K with angle-resolved thermal desorption. N2 desorption showed five peaks at around 70 K (β5-N2), 95 K (β4-N2), 115 K (β3-N2), 140 K (β2-N2), and 160 K (β1-N2). β1-N2 yielded a cosine distribution, whereas the others involved desorption components that collimated at either 69±3° or 27±3° off normal into the [0 0 1] direction. The 27° component was suppressed on clean (1×1) facets. The 69° component is proposed to be due to decomposition of N 2O oriented in the [0 0 1] direction.

AB - The angular distribution of desorbing N2 was studied in the decomposition of N2O(a) on Rh(1 1 0) at 50-200 K with angle-resolved thermal desorption. N2 desorption showed five peaks at around 70 K (β5-N2), 95 K (β4-N2), 115 K (β3-N2), 140 K (β2-N2), and 160 K (β1-N2). β1-N2 yielded a cosine distribution, whereas the others involved desorption components that collimated at either 69±3° or 27±3° off normal into the [0 0 1] direction. The 27° component was suppressed on clean (1×1) facets. The 69° component is proposed to be due to decomposition of N 2O oriented in the [0 0 1] direction.

KW - Angle resolved DIET (including electron stimulated desorption ion angular distribution (ESDIAD))

KW - Catalysis

KW - Nitrogen oxides

KW - Rhodium

KW - Surface chemical reaction

KW - Thermal desorption

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DO - 10.1016/j.susc.2004.06.054

M3 - Conference article

AN - SCOPUS:4544257362

SN - 0039-6028

VL - 566-568

SP - 1076

EP - 1081

JO - Surface Science

JF - Surface Science

IS - 1-3 PART 2

T2 - Proceedings of the 22nd European Conference on Surface Science

Y2 - 7 September 2003 through 12 September 2003

ER -