Nitrogen removal pathways in a steady-state NO + CO reaction on Pd(110)

Yunsheng Ma, Izabela Irena Rzeznicka, Tatsuo Matsushima

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Three removal processes of surface nitrogen, i.e., (i) the decomposition of the intermediate N2O(a), (ii) its desorption without decomposition and (iii) the associative desorption of nitrogen atoms, were separately studied in a steady-state NO+CO reaction on Pd(110) through analysis of the angular and velocity distributions of desorbing products N2 and N2O. At temperatures below approximately 600 K, the processes (i) and (ii) prevailed, whereas at higher temperatures, the process (iii) contributed significantly. The branching was also sensitive to the CO/NO pressure ratio.

Original languageEnglish
Pages (from-to)201-207
Number of pages7
JournalChemical Physics Letters
Volume388
Issue number1-3
DOIs
Publication statusPublished - 2004 Apr 11
Externally publishedYes

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Nitrogen removal
Carbon Monoxide
Desorption
Nitrogen
desorption
Decomposition
decomposition
nitrogen
pressure ratio
Angular distribution
Velocity distribution
nitrogen atoms
angular distribution
velocity distribution
Atoms
Temperature
products
temperature

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Cite this

Nitrogen removal pathways in a steady-state NO + CO reaction on Pd(110). / Ma, Yunsheng; Rzeznicka, Izabela Irena; Matsushima, Tatsuo.

In: Chemical Physics Letters, Vol. 388, No. 1-3, 11.04.2004, p. 201-207.

Research output: Contribution to journalArticle

Ma, Yunsheng ; Rzeznicka, Izabela Irena ; Matsushima, Tatsuo. / Nitrogen removal pathways in a steady-state NO + CO reaction on Pd(110). In: Chemical Physics Letters. 2004 ; Vol. 388, No. 1-3. pp. 201-207.
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