Novel thermosensitive polyethers prepared by anionic ring-opening polymerization of glycidyl ether derivatives

Sayuri Aoki; Aya Koide; Shin Ichiro Imabayashi; Masayoshi Watanabe

doi:10.1246/cl.2002.1128

Novel thermosensitive polyethers prepared by anionic ring-opening polymerization of glycidyl ether derivatives

Sayuri Aoki, Aya Koide, Shin Ichiro Imabayashi, Masayoshi Watanabe

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

A new series of thermo-sensitive polyethers were prepared by anionic ring-opening polymerization of glycidyl ether derivatives: glycidyl methyl ether, ethyl glycidyl ether, and ethoxyethyl glycidyl ether. The prepared polymers have controllable molecular weight with narrow molecular weight distributions. These polymers exhibit a lower critical solution temperature (LCST) in water. The LCST is altered from 14.6 to 57.7°C by decreasing the hydrophobicity of the side-chain units.

Original language	English
Pages (from-to)	1128-1129
Number of pages	2
Journal	Chemistry Letters
Issue number	11
DOIs	https://doi.org/10.1246/cl.2002.1128
Publication status	Published - 2002 Nov 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2002.1128

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abstract = "A new series of thermo-sensitive polyethers were prepared by anionic ring-opening polymerization of glycidyl ether derivatives: glycidyl methyl ether, ethyl glycidyl ether, and ethoxyethyl glycidyl ether. The prepared polymers have controllable molecular weight with narrow molecular weight distributions. These polymers exhibit a lower critical solution temperature (LCST) in water. The LCST is altered from 14.6 to 57.7°C by decreasing the hydrophobicity of the side-chain units.",

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AU - Aoki, Sayuri

AU - Koide, Aya

AU - Imabayashi, Shin Ichiro

AU - Watanabe, Masayoshi

PY - 2002/11/5

Y1 - 2002/11/5

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AB - A new series of thermo-sensitive polyethers were prepared by anionic ring-opening polymerization of glycidyl ether derivatives: glycidyl methyl ether, ethyl glycidyl ether, and ethoxyethyl glycidyl ether. The prepared polymers have controllable molecular weight with narrow molecular weight distributions. These polymers exhibit a lower critical solution temperature (LCST) in water. The LCST is altered from 14.6 to 57.7°C by decreasing the hydrophobicity of the side-chain units.

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ER -

Novel thermosensitive polyethers prepared by anionic ring-opening polymerization of glycidyl ether derivatives

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