Novel thermosensitive polyethers prepared by anionic ring-opening polymerization of glycidyl ether derivatives

Sayuri Aoki; Aya Koide; Shin Ichiro Imabayashi; Masayoshi Watanabe

doi:10.1246/cl.2002.1128

Novel thermosensitive polyethers prepared by anionic ring-opening polymerization of glycidyl ether derivatives

Sayuri Aoki, Aya Koide, Shin Ichiro Imabayashi, Masayoshi Watanabe

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

A new series of thermo-sensitive polyethers were prepared by anionic ring-opening polymerization of glycidyl ether derivatives: glycidyl methyl ether, ethyl glycidyl ether, and ethoxyethyl glycidyl ether. The prepared polymers have controllable molecular weight with narrow molecular weight distributions. These polymers exhibit a lower critical solution temperature (LCST) in water. The LCST is altered from 14.6 to 57.7°C by decreasing the hydrophobicity of the side-chain units.

Original language	English
Pages (from-to)	1128-1129
Number of pages	2
Journal	Chemistry Letters
Issue number	11
DOIs	https://doi.org/10.1246/cl.2002.1128
Publication status	Published - 2002 Nov 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/cl.2002.1128

Fingerprint Dive into the research topics of 'Novel thermosensitive polyethers prepared by anionic ring-opening polymerization of glycidyl ether derivatives'. Together they form a unique fingerprint.

Cite this

@article{69cc2c18f9a84f39861c1da31116a6ef,

title = "Novel thermosensitive polyethers prepared by anionic ring-opening polymerization of glycidyl ether derivatives",

abstract = "A new series of thermo-sensitive polyethers were prepared by anionic ring-opening polymerization of glycidyl ether derivatives: glycidyl methyl ether, ethyl glycidyl ether, and ethoxyethyl glycidyl ether. The prepared polymers have controllable molecular weight with narrow molecular weight distributions. These polymers exhibit a lower critical solution temperature (LCST) in water. The LCST is altered from 14.6 to 57.7°C by decreasing the hydrophobicity of the side-chain units.",

author = "Sayuri Aoki and Aya Koide and Imabayashi, {Shin Ichiro} and Masayoshi Watanabe",

year = "2002",

month = nov,

day = "5",

doi = "10.1246/cl.2002.1128",

language = "English",

pages = "1128--1129",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "11",

}

TY - JOUR

T1 - Novel thermosensitive polyethers prepared by anionic ring-opening polymerization of glycidyl ether derivatives

AU - Aoki, Sayuri

AU - Koide, Aya

AU - Imabayashi, Shin Ichiro

AU - Watanabe, Masayoshi

PY - 2002/11/5

Y1 - 2002/11/5

N2 - A new series of thermo-sensitive polyethers were prepared by anionic ring-opening polymerization of glycidyl ether derivatives: glycidyl methyl ether, ethyl glycidyl ether, and ethoxyethyl glycidyl ether. The prepared polymers have controllable molecular weight with narrow molecular weight distributions. These polymers exhibit a lower critical solution temperature (LCST) in water. The LCST is altered from 14.6 to 57.7°C by decreasing the hydrophobicity of the side-chain units.

AB - A new series of thermo-sensitive polyethers were prepared by anionic ring-opening polymerization of glycidyl ether derivatives: glycidyl methyl ether, ethyl glycidyl ether, and ethoxyethyl glycidyl ether. The prepared polymers have controllable molecular weight with narrow molecular weight distributions. These polymers exhibit a lower critical solution temperature (LCST) in water. The LCST is altered from 14.6 to 57.7°C by decreasing the hydrophobicity of the side-chain units.

UR - http://www.scopus.com/inward/record.url?scp=0037027692&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037027692&partnerID=8YFLogxK

U2 - 10.1246/cl.2002.1128

DO - 10.1246/cl.2002.1128

M3 - Article

AN - SCOPUS:0037027692

SP - 1128

EP - 1129

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 11

ER -