O1s core levels of Bi-Sr-Ca-Cu-O superconductors studied by X-ray photoelectron spectroscopy

M. Nagoshi; Y. Fukuda; N. Sanada; Y. Syono; Ayako Yamamoto; M. Tachiki

doi:10.1016/0368-2048(93)80022-E

O1s core levels of Bi-Sr-Ca-Cu-O superconductors studied by X-ray photoelectron spectroscopy

M. Nagoshi, Y. Fukuda, N. Sanada, Y. Syono, Ayako Yamamoto, M. Tachiki

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Abstract

The O1s core level spectra recorded for the Bi₂Sr₂Ca_n-1Cu_nO_2n+2+δ (n = 1, 2, and 3) oxides are investigated by taking into account the layered structures, the well developed cleavage between double Bi-O layers, and the surface sensitivity of photoelectron spectroscopy. The results show that the O1s core lines with binding energies of 527.9, 528.7, and 529.4 eV can be attributed to oxygen atoms in the Cu-O₂, Bi-O, and Sr-O layers, respectively. In the Bi₂Sr₂Ca_1-xY_xCu₂O_y system, the O1s line corresponding to oxygen atoms in the Cu-O₂ planes shifts significantly to the high binding energy side with the substitution of Y for Ca. These results are discussed in terms of hole concentrations of metal-oxygen bonds.

Original language	English
Pages (from-to)	309-322
Number of pages	14
Journal	Journal of Electron Spectroscopy and Related Phenomena
Volume	61
Issue number	3-4
DOIs	https://doi.org/10.1016/0368-2048(93)80022-E
Publication status	Published - 1993 Feb 26
Externally published	Yes

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ASJC Scopus subject areas

Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics
Surfaces and Interfaces

Cite this

Nagoshi, M., Fukuda, Y., Sanada, N., Syono, Y., Yamamoto, A., & Tachiki, M. (1993). O1s core levels of Bi-Sr-Ca-Cu-O superconductors studied by X-ray photoelectron spectroscopy. Journal of Electron Spectroscopy and Related Phenomena, 61(3-4), 309-322. https://doi.org/10.1016/0368-2048(93)80022-E

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title = "O1s core levels of Bi-Sr-Ca-Cu-O superconductors studied by X-ray photoelectron spectroscopy",

abstract = "The O1s core level spectra recorded for the Bi2Sr2Can-1CunO2n+2+δ (n = 1, 2, and 3) oxides are investigated by taking into account the layered structures, the well developed cleavage between double Bi-O layers, and the surface sensitivity of photoelectron spectroscopy. The results show that the O1s core lines with binding energies of 527.9, 528.7, and 529.4 eV can be attributed to oxygen atoms in the Cu-O2, Bi-O, and Sr-O layers, respectively. In the Bi2Sr2Ca1-xYxCu2Oy system, the O1s line corresponding to oxygen atoms in the Cu-O2 planes shifts significantly to the high binding energy side with the substitution of Y for Ca. These results are discussed in terms of hole concentrations of metal-oxygen bonds.",

author = "M. Nagoshi and Y. Fukuda and N. Sanada and Y. Syono and Ayako Yamamoto and M. Tachiki",

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T1 - O1s core levels of Bi-Sr-Ca-Cu-O superconductors studied by X-ray photoelectron spectroscopy

AU - Nagoshi, M.

AU - Fukuda, Y.

AU - Sanada, N.

AU - Syono, Y.

AU - Yamamoto, Ayako

AU - Tachiki, M.

PY - 1993/2/26

Y1 - 1993/2/26

N2 - The O1s core level spectra recorded for the Bi2Sr2Can-1CunO2n+2+δ (n = 1, 2, and 3) oxides are investigated by taking into account the layered structures, the well developed cleavage between double Bi-O layers, and the surface sensitivity of photoelectron spectroscopy. The results show that the O1s core lines with binding energies of 527.9, 528.7, and 529.4 eV can be attributed to oxygen atoms in the Cu-O2, Bi-O, and Sr-O layers, respectively. In the Bi2Sr2Ca1-xYxCu2Oy system, the O1s line corresponding to oxygen atoms in the Cu-O2 planes shifts significantly to the high binding energy side with the substitution of Y for Ca. These results are discussed in terms of hole concentrations of metal-oxygen bonds.

AB - The O1s core level spectra recorded for the Bi2Sr2Can-1CunO2n+2+δ (n = 1, 2, and 3) oxides are investigated by taking into account the layered structures, the well developed cleavage between double Bi-O layers, and the surface sensitivity of photoelectron spectroscopy. The results show that the O1s core lines with binding energies of 527.9, 528.7, and 529.4 eV can be attributed to oxygen atoms in the Cu-O2, Bi-O, and Sr-O layers, respectively. In the Bi2Sr2Ca1-xYxCu2Oy system, the O1s line corresponding to oxygen atoms in the Cu-O2 planes shifts significantly to the high binding energy side with the substitution of Y for Ca. These results are discussed in terms of hole concentrations of metal-oxygen bonds.

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10.1016/0368-2048(93)80022-E