Abstract
The adsorption structure of N2O on Pd(1 1 0) was analyzed below 14 K by scanning-tunneling microscopy. The N2O monomer was oriented along the [0 0 1] direction in the on-top form. Furthermore, the formation of small aggregates extending along the [11̄0] direction was observed. The observed images were well-simulated for two types of cluster structures optimized by density-functional theory calculations. The components in the aggregates are proposed to be in a tilted form either on bridge sites or on-top sites.
| Original language | English |
|---|---|
| Pages (from-to) | 474-478 |
| Number of pages | 5 |
| Journal | Chemical Physics Letters |
| Volume | 406 |
| Issue number | 4-6 |
| DOIs | |
| Publication status | Published - 2005 May 2 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Spectroscopy
- Atomic and Molecular Physics, and Optics
- Surfaces and Interfaces
- Condensed Matter Physics
Cite this
Orientation of nitrous oxide on palladium(1 1 0) by STM. / Watanabe, Kazuo; Kokalj, Anton; Inokuchi, Yoshiya; Rzeznicka, Izabela Irena; Ohshimo, Keijiro; Nishi, Nobuyuki; Matsushima, Tatsuo.
In: Chemical Physics Letters, Vol. 406, No. 4-6, 02.05.2005, p. 474-478.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Orientation of nitrous oxide on palladium(1 1 0) by STM
AU - Watanabe, Kazuo
AU - Kokalj, Anton
AU - Inokuchi, Yoshiya
AU - Rzeznicka, Izabela Irena
AU - Ohshimo, Keijiro
AU - Nishi, Nobuyuki
AU - Matsushima, Tatsuo
PY - 2005/5/2
Y1 - 2005/5/2
N2 - The adsorption structure of N2O on Pd(1 1 0) was analyzed below 14 K by scanning-tunneling microscopy. The N2O monomer was oriented along the [0 0 1] direction in the on-top form. Furthermore, the formation of small aggregates extending along the [11̄0] direction was observed. The observed images were well-simulated for two types of cluster structures optimized by density-functional theory calculations. The components in the aggregates are proposed to be in a tilted form either on bridge sites or on-top sites.
AB - The adsorption structure of N2O on Pd(1 1 0) was analyzed below 14 K by scanning-tunneling microscopy. The N2O monomer was oriented along the [0 0 1] direction in the on-top form. Furthermore, the formation of small aggregates extending along the [11̄0] direction was observed. The observed images were well-simulated for two types of cluster structures optimized by density-functional theory calculations. The components in the aggregates are proposed to be in a tilted form either on bridge sites or on-top sites.
UR - http://www.scopus.com/inward/record.url?scp=16844385854&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=16844385854&partnerID=8YFLogxK
U2 - 10.1016/j.cplett.2005.03.033
DO - 10.1016/j.cplett.2005.03.033
M3 - Article
AN - SCOPUS:16844385854
VL - 406
SP - 474
EP - 478
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 4-6
ER -