Orientation of nitrous oxide on palladium(1 1 0) by STM

Kazuo Watanabe, Anton Kokalj, Yoshiya Inokuchi, Izabela Rzeznicka, Keijiro Ohshimo, Nobuyuki Nishi, Tatsuo Matsushima

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24 Citations (Scopus)

Abstract

The adsorption structure of N2O on Pd(1 1 0) was analyzed below 14 K by scanning-tunneling microscopy. The N2O monomer was oriented along the [0 0 1] direction in the on-top form. Furthermore, the formation of small aggregates extending along the [11̄0] direction was observed. The observed images were well-simulated for two types of cluster structures optimized by density-functional theory calculations. The components in the aggregates are proposed to be in a tilted form either on bridge sites or on-top sites.

Original languageEnglish
Pages (from-to)474-478
Number of pages5
JournalChemical Physics Letters
Volume406
Issue number4-6
DOIs
Publication statusPublished - 2005 May 2

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ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Watanabe, K., Kokalj, A., Inokuchi, Y., Rzeznicka, I., Ohshimo, K., Nishi, N., & Matsushima, T. (2005). Orientation of nitrous oxide on palladium(1 1 0) by STM. Chemical Physics Letters, 406(4-6), 474-478. https://doi.org/10.1016/j.cplett.2005.03.033